罗纹织物增强改性PBAT基复合材料的制备及力学性能探究

Study on the preparation and mechanical properties of PBAT matrix composite reinforced by cotton ribbed fabric

  • 摘要: 为了提高聚己二酸对苯二甲酸丁二醇酯(PBAT)复合材料在小应变时的拉伸模量从而能承载或包覆重物,本文以10wt.% CaCO3填充聚乳酸(PLA)-PBAT形状记忆复合膜为预制体,自制的棉罗纹织物为骨架材料,通过吹膜和热压成型工艺制备了单面(S系列)和双面(D系列)棉罗纹织物增强CaCO3/PLA-PBAT复合材料,并研究预制体及棉罗纹织物对该复合材料的拉伸性能、顶破强力性能、耐撕裂性能、形状记忆性能、耐磨性能和湿润性能的影响。结果表明:当预制体质量含量较少时,S系列复合材料表现为针织物的力学特性,随着应变增加,应力-应变曲线呈波浪状;当预制体质量含量较多时,其模量显著提高,最高达到1048.7±49.9MPa。S系列和D系列复合材料纵向和横向的撕裂强度均随着预制体树脂含量的增加而增大;D系列复合材料纵向形状记忆固定率(Rf)平均值均大于60%,纵向120℃条件下其形状记忆回复率(Rr)最大值为91.90%±1.56%,另外,预制体含量对纵向Rr影响较小,但随着预制体含量的增加,纵向Rr有小幅度的提高。本文为高模量PBAT基形状记忆复合材料的设计与制备提供了理论参考,并为其在高性能热收缩膜领域的应用与研究拓展了新的视角。

     

    Abstract: In order to improve the tensile modulus of polybutylene adipate-co-terephthalate(PBAT) composite material under small strain so as to load or cover heavy objects, the paper uses polylactic acid(PLA)-PBAT shape memory composite film filled with 10wt.% CaCO3 as prefabricated body and homemade cotton ribbed fabric as skeleton material. CaCO3/PLA-PBAT composites reinforced by single side (S series) and double side (D series) cotton ribbed fabric were prepared by blowing film and hot pressing process. The effects of preform and cotton ribbed fabric on the tensile property, bursting strength, tear resistance, shape memory, friction resistance and wetting properties of the composites were investigated. The results show that the S-series composites exhibit the mechanical properties of knitted fabric when the mass content of prefabricated body is low, and the stress curve is wavy with the increase of strain. When the mass content of the precast is higher, the modulus of the composite increases significantly, reaching 1048.7±49.9MPa. The longitudinal and transverse tear strength of S series and D series composites increases with the increase of resin content in the preform. The average longitudinal shape memory fixation rate(Rf) of D series composites is greater than 60%, and the maximum shape memory recovery rate(Rr) is 91.90%±1.56% at 120℃. In addition, the preform content has little influence on the longitudinal Rr, but with the increase of the preform content, the longitudinal Rr increases slightly. This paper provides a theoretical reference for the design and preparation of high modulus PBAT-based shape memory composites, and expands a new perspective for its application and research in the field of high performance heat shrink films.

     

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