固废基多孔骨料对高强水泥基复合材料自收缩变形的调控机制

Regulation mechanism of autogenous shrinkage in high-strength cementitious composites by solid waste-based porous aggregate

  • 摘要: 为阐明重金属污泥烧结多孔骨料(porous aggregate,PA)对高强水泥基复合材料自收缩变形的调控作用及其温度响应机制,本文制备了PA体积取代率为0%、10%、20%、30%和40%的高强水泥基复合材料,并在10℃、20℃和30℃条件下开展流动度、力学性能和7 d自收缩变形测试。采用XRD、FTIR、TG/DTG和低场氢核磁共振(1H NMR)分析水化产物演化与水分迁移行为。结果表明,PA使拌合物流动度由312 mm降低至143 mm,但显著提高早期抗压强度,40vol% PA组1 d抗压强度较基准组提高27.27%。在20℃条件下,基准组7 d自收缩为523.87 με,而40vol% PA组实现收缩补偿并产生约167 με膨胀;在30℃条件下,膨胀变形超过200 με。微观结果表明,PA促进C3S和C2S消耗,提高Ca(OH)2、AFt和化学结合水含量,并通过持续释水延缓内部湿度下降。PA对自收缩的调控来源于多孔储水、湿度响应释水、持续水化促进、游离CaO水化膨胀和骨架约束的协同作用。研究结果表明,重金属污泥烧结PA可作为兼具固废资源化利用与收缩调控功能的绿色内养护骨料。

     

    Abstract: To clarify the regulation effect of porous aggregate (PA) sintered from heavy metal sludge on the autogenous shrinkage of high-strength cementitious composites and its temperature-dependent mechanism, composites with PA volume replacement ratios of 0%, 10%, 20%, 30%, and 40% were prepared and cured at 10℃, 20℃, and 30℃. Fluidity, mechanical properties, and 7 d autogenous shrinkage were measured. XRD, FTIR, TG/DTG, and low-field proton nuclear magnetic resonance (1H NMR) were used to analyze hydration products and moisture migration. The results show that PA decreases the fluidity from 312 mm to 143 mm, but increases the early compressive strength; the 1 d compressive strength of the composite with 40% PA is increased by 27.27%. At 20℃, the reference group exhibits a 7 d autogenous shrinkage of 523.87 με, whereas the composite with 40vol% PA compensates for shrinkage and shows an expansion of approximately 167 με. At 30 ℃, the expansion exceeds 200 με. Microstructural results indicate that PA promotes the consumption of C3S and C2S, increases the contents of Ca(OH)2, AFt, and chemically bound water, and delays internal humidity reduction through continuous water release. The regulation of autogenous shrinkage by PA results from the synergistic effects of porous water storage, humidity-responsive water release, continuous hydration promotion, free-CaO hydration expansion, and skeleton restraint. These findings indicate that heavy-metal-sludge-derived PA can be used as a green internal curing aggregate for both solid waste utilization and shrinkage control.

     

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