纳米TiC颗粒对再生A356.2铝合金显微组织和力学性能的影响

Influence of nano-TiC particle on the microstructure and mechanical properties of recycled A356.2 aluminum alloy

  • 摘要: 再生A356.2铝合金在低碳制造与资源循环利用背景下具有重要应用前景,但其在多次回收过程中易富集Fe杂质并形成针状β-Al5FeSi相,同时与粗大的α-Al枝晶和片状共晶Si相共同作用,显著降低合金的力学性能。对TiC纳米颗粒调控再生A356.2铝合金组织与性能进行了研究。采用球磨-冷压结合真空电弧熔炼制备Al-20TiC中间合金,并通过搅拌铸造工艺制备含0、0.5、1.0和1.5vol.%TiC的TiC/A356.2复合材料,利用XRD、SEM及冷却曲线分析等方法表征其凝固行为、显微组织及力学性能。结果表明,TiC纳米颗粒在铝基体中保持稳定存在并作为有效异质形核核心,使α-Al形核温度由615.8℃提高至617.9℃,二次枝晶臂间距由20.16 μm降低至15.4 μm;同时显著细化了共晶Si相,其尺寸由4.06 μm降低至0.79 μm,长径比由2.68降至1.63,并减小针状β-Al5FeSi相尺寸。当TiC含量为1.0vol.%时复合材料性能最佳,屈服强度、抗拉强度和伸长率分别达到264.1 MPa、285.6 MPa和11.5%。力学性能的提高主要归因于共晶Si球化、β-Al5FeSi相细化的协同作用。

     

    Abstract: Recycled A356.2 aluminum alloy holds significant application prospects in the context of low-carbon manufacturing and resource recycling. However, during multiple recycling processes, it is highly susceptible to the enrichment of Fe impurities and the subsequent formation of the acicular β-Al5FeSi phase. This, coupled with the presence of coarse α-Al dendrites and flake-like eutectic Si phases, significantly degrades the mechanical properties of the alloy. In this study, the regulation of the microstructure and properties of recycled A356.2 aluminum alloy by TiC nanoparticles was investigated. An Al-20TiC master alloy was prepared using a combination of ball milling, cold pressing, and vacuum arc melting. Subsequently, TiC/A356.2 composites containing 0, 0.5, 1.0, and 1.5vol.%TiC were fabricated via a stir casting process. The solidification behavior, microstructure, and mechanical properties were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and cooling curve analysis. The results indicate that TiC nanoparticles remain stable within the aluminum matrix and act as effective heterogeneous nucleation sites, increasing the nucleation temperature of α-Al from 615.8℃ to 617.9℃ and reducing the secondary dendrite arm spacing (SDAS) from 20.16 μm to 15.4 μm. Simultaneously, the eutectic Si phase is significantly refined, with its size decreasing from 4.06 μm to 0.79 μm and its aspect ratio dropping from 2.68 to 1.63, while the size of the acicular β-Al5FeSi phase is also notably reduced. The composite exhibits optimal performance at a TiC addition of 1.0vol.%, where the yield strength, ultimate tensile strength, and elongation reach 264.1 MPa, 285.6 MPa, and 11.5%, respectively. The enhancement in mechanical properties is primarily attributed to the synergistic effects of eutectic Si spheroidization, β-Al5FeSi phase refinement.

     

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