铅锌尾矿基三元复合浆料的抗水力侵蚀性及微观结构演化

Hydraulic erosion resistance and microstructure evolution of lead-zinc tailings-based ternary composite grout

  • 摘要: 研制模拟海水拌合铅锌尾矿渣、碱渣和粉煤灰三元复合浆料,旨在为消纳三种固废提供新途径并节约水资源。通过强度、渗透和干缩试验探究不同配比下浆料固结体的抗水力侵蚀性能,结合扫描电镜-能谱(SEM-EDS)、热重-差示扫描量热(TG-DSC)、原子力显微镜(AFM)和压汞法(MIP)测试探明固结体宏观性能演化机制。结果表明,模拟海水协同碱渣与粉煤灰促使水化产物的产生,形成致密且光滑的表面形貌并表现出更高的弹性模量,有助于基体内孔隙填充和密实度提升,因而高碱渣掺量固结体表现出优异的抗水力侵蚀性。相反,高掺量尾矿渣抑制基体内水化反应,减少了凝胶数量并增多了孔隙,抑制了其宏观性能的发展。掺有48%碱渣和40%尾矿渣的浆料在固化28 d后具有较高的水蚀抗压强度(3.45 MPa)和较低的渗透系数(在1.5MPa水压下为3.64×10−7 cm/s),在干缩4~25 d中的体积收缩率较小稳定在0.014~0.047。浆料在固化28 d后因重金属的化学形态逐渐转变为稳定惰性形态,展现出极低的浸出毒性和较低的环境污染风险。总的来说,新型复合浆料有助于多固废综合利用并展现出良好的经济环境效益。

     

    Abstract: The artificial seawater-mixed ternary composite grout composed of lead-zinc tailings, soda residue, and fly ash was developed to offer a new pathway for utilizing three solid wastes and conserving water resources. The hydraulic erosion resistance of solidified grouts with various mix proportions was investigated through strength, permeability, and drying shrinkage tests, and the evolution mechanisms of their macro performance were elucidated using SEM-EDS, TG-DSC, AFM, and MIP tests. The results indicate that artificial seawater, in conjunction with soda residue and fly ash, promotes the formation of hydration products, resulting in a denser and smoother surface morphology and a higher elastic modulus. These effects enhance pore filling and improve matrix compactness, leading to superior hydraulic erosion resistance in grouts with a high ratio of soda residue. In contrast, excessive lead-zinc tailings inhibit hydration reactions, reduce gel formation, and increase porosity, thereby weakening its macro performance development. The grout containing 48% soda residue and 40% lead-zinc tailings exhibits great water corrosion compressive strength (3.45 MPa) and low permeability coefficient (3.64×10-7 cm/s under 1.5 MPa water pressure) after curing at 28 days, and its shrinkage ratio stabilizes at 0.014~0.047 during 4 to 25 drying days. After curing at 28 days, the chemical speciation of heavy metals in the grout gradually transforms into stable and inert forms, exhibiting low leaching toxicity and minimal environmental pollution risk. Overall, the new composite grout contributes to the comprehensive utilization of multiple solid wastes and demonstrates significant economic and environmental benefits.

     

/

返回文章
返回