混杂纤维超高性能混凝土高温爆裂抑制与矿化养护修复机理研究

Study on the mechanism of high-temperature spalling inhibition and mineralization curing repair for hybrid fiber-reinforced ultra-high performance concrete

  • 摘要: 超高性能混凝土(UHPC)极低的水胶比,使其在工程应用中面临着高温爆裂和损伤后强度恢复困难等问题,使用混杂纤维和二次养护是一种有效的解决办法。本文采用钢-聚丙烯(PP)混杂纤维提高UHPC基体的高温体积稳定性,并对经历300℃、600℃及900℃高温后的受损试件分别进行饱和石灰水喷淋养护和水-CO2循环养护。基于抗压强度测试、扫描电镜(SEM)及压汞法(MIP)对其力学性能和微观结构进行了评价。研究结果表明,3vol%钢纤维与0.4vol%PP纤维的混杂协同有效抑制了高温爆裂,确保试件在900℃高温后质量损失率仅为8.62%,维持了UHPC基体的完整性,为强度恢复提供了必要的载体。在修复阶段,水-CO2循环养护展现出显著的效率优势,仅需7 d即可达到饱和石灰水喷淋养护30 d的强度恢复水平,并可将900℃试件的残余抗压强度从41.0 MPa提升至81.5 MPa。微观结构分析证实,水-CO2循环引发了高效矿化反应,生成的碳酸钙晶体与凝胶产物共同填充了热损伤裂缝,使900℃受损试件的总孔隙率从20.5%降至5.0%。综上表明,钢-PP混杂纤维的物理阻裂与水-CO2循环养护的微观修复相结合,可有效提升UHPC的抗高温性能,并实现热损伤后力学性能的恢复。

     

    Abstract: Ultra-high performance concrete (UHPC) is faced with problems such as high-temperature spalling and difficulty in post-damage strength recovery in engineering applications due to its extremely low water-binder ratio. One of the effective solutions is the incorporation of hybrid fibers and the application of secondary curing. In this study, steel-polypropylene (PP) hybrid fibers were used to improve the high-temperature volumetric stability of the matrix. The damaged specimens exposed to high temperatures of 300℃, 600℃, and 900℃ were separately subjected to spray curing with lime-saturated water and water-CO2 cyclic curing. The mechanical properties and microstructures were evaluated through compressive strength tests, scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). The results show that the hybrid effect of 3vol% steel fibers and 0.4vol% PP fibers effectively inhibited high-temperature spalling, ensuring a mass loss rate of only 8.62% for specimens after 900℃ exposure. This maintained the integrity of the UHPC matrix and provided a necessary carrier for strength recovery. During the repair phase, water-CO2 cyclic curing demonstrated remarkable efficiency, achieving the same strength recovery level in just 7 days as 30 days of spray curing with lime-saturated water. Furthermore, it increased the residual compressive strength of the 900℃ specimens from 41.0 MPa to 81.5 MPa. Microstructural analysis confirmed that the water-CO2 cycle induced a highly efficient mineralization reaction, where the generated calcium carbonate crystals and gel products jointly filled the thermal damage cracks, reducing the total porosity of the 900℃ damaged specimens from 20.5% to 5.0%. In summary, the combination of the physical crack inhibition of steel-PP hybrid fibers and the microstructural repair of water-CO2 cyclic curing can effectively enhance the high-temperature resistance of UHPC and achieve the recovery of mechanical properties after thermal damage.

     

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