高填充木粉/聚丙烯复合材料的压缩流变行为

Compression rheological behavior of highly filled wood flour/polypropylene composites

  • 摘要: 高填充木塑复合材料有着更高的低碳环保性和市场竞争优势,探究其在熔融过程中的流变行为对优化生产装备、提高生产效率具有重要意义。本文采用自制的压缩测试系统分析了高填充木粉/聚丙烯复合材料(HFWFPP)在连续变形下的流变特性。对HFWFPP在压缩过程中的形态变化进行了记录分析,将测试数据与plug flow模型结合,探讨了其流变行为。结果表明,压缩测试有效诱导了试样的大范围均匀流动,为流变行为的准确表达创造了前提条件。基于plug flow模型对试样不同应力进行计算和分析,验证了该模型在HFWFPP的压缩流变的适用性,阐明了HFWFPP的压缩流变行为。并据此量化了不同木粉含量、初始半径及偶联剂对试样流变特性的影响。为高填充木塑复合材料提供了一种有效的流变分析方法,为其生产和应用提供了理论借鉴。

     

    Abstract: Highly filled wood-plastic composites have better low carbon and environmental protection and market competition advantages. Investigating their rheological behavior during the melting process is of significant importance for optimizing production equipment and improving production efficiency. In this study, the rheological properties of highly filled wood flour/polypropylene composites (HFWFPP) under continuous deformation were analyzed by a homemade compression testing system. The morphological changes of HFWFPP during compression were recorded and analyzed, and the test data were combined with the plug flow model to explore its rheological behavior. The results show that the compression test effectively induced a large-scale uniform flow of the specimens, creating a prerequisite for the accurate expression of rheological behavior. The stresses of the specimen were calculated and analyzed based on the plug flow model, validating the applicability of the model to the compression rheology of HFWFPP and elucidating its compression rheological behavior. Based on this, the influence of wood flour content, initial radius, and coupling agent on the rheological properties of the specimen was quantified. This study provides an effective rheological analysis method for highly filled wood-plastic composites and offers theoretical insights for their production and application.

     

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