高温养护与埃洛石纳米管协同作用对地聚合物混凝土力学性能及反应机理的影响

Synergistic effect of elevated curing temperatures and halloysite nanotubes on the mechanical properties and reaction mechanism of geopolymer concrete

  • 摘要: 针对地聚合物混凝土(GPC)在高温养护环境下易出现反应不充分或孔隙缺陷导致力学性能下降的问题,本研究旨在探究高温养护与埃洛石纳米管(HNTs)的协同作用机制,实现高地温环境下适配型GPC的性能调控。以20、40、60和80℃为温度梯度,采用粉煤灰(FA)和粒化高炉矿渣(GGBS)为前驱体材料,2.0wt%的HNTs为增强改性材料制备GPC,通过FTIR、XRD、TGA及SEM等微观测试技术,系统探究养护温度与HNTs协同作用对GPC力学性能的影响及内在机制。结果表明:20~40℃时前驱体反应不充分,体系残留大量未反应颗粒、溶胶相及水分,导致基体结构疏松、强度偏低;温度升至60℃,Si-O-T吸收峰波数最低,水分扩散促进地聚合反应,凝胶量显著增加,基体致密化程度提升,其中掺HNTs的60-H组优化效果最突出,28 d抗压强度达66.6 MPa、劈裂抗拉强度达3.40 MPa,较同温度下未掺HNTs的60-C组分别提升11.0%、12.9%。HNTs通过“晶种成核”效应加速聚合反应,促进石英相溶解,减少孔隙数量与孔径,进而提升力学性能。80℃时Si-O-T吸收峰波数升高,聚合度降低,过高温度导致凝胶骤增包裹原材料并引发水分快速蒸发,阻碍反应进行,形成大量连通且松散的孔隙,最终导致GPC力学性能下降。

     

    Abstract: In view of the problem that geopolymer concrete (GPC) is prone to insufficient reaction or pore defects under elevated curing temperature conditions, which leads to the degradation of mechanical properties, this study aims to explore the synergistic mechanism of elevated curing temperature and halloysite nanotubes (HNTs) for the performance regulation of GPC adaptable to high geothermal environments. GPC was prepared using fly ash (FA) and ground granulated blast furnace slag (GGBS) as precursor materials, with 2.0wt% HNTs as the reinforcing and modifying material, and temperature gradients of 20, 40, 60, and 80℃ were set. Through micro-testing techniques such as FTIR, XRD, TGA, and SEM, the synergistic effects of curing temperature and HNTs on the mechanical properties of GPC and the underlying mechanisms were systematically investigated. The results showed that at 20~40℃, the precursors reacted insufficiently, with a large amount of unreacted particles, sol phases, and moisture remaining in the system, leading to a loose matrix structure and relatively low strength. When the temperature rose to 60℃, the wavenumber of the Si-O-T absorption peak was the lowest, and moisture diffusion promoted the geopolymerization reaction, significantly increasing the gel content and improving the matrix compactness. Among all groups, the 60-H group (with HNTs) exhibited the most prominent optimization effect: its 28-day compressive strength reached 66.6 MPa and splitting tensile strength reached 3.40 MPa, which were 11.0% and 12.9% higher than those of the 60-C group (without HNTs) cured at the same temperature. HNTs accelerated the polymerization reaction through the "seed nucleation" effect, promoted the dissolution of quartz phase, and reduced the number and size of pores, thereby enhancing the mechanical properties of GPC. At 80℃, however, the wavenumber of the Si-O-T absorption peak increased and the degree of polymerization decreased. Excessively high temperature caused a sharp increase in gel content that wrapped around raw material particles and induced rapid moisture evaporation, hindering the continuation of the reaction and forming a large number of connected and loose pores, which ultimately led to the degradation of GPC mechanical properties.

     

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