电流密度对超声脉冲电沉积Ni-Co-P/SiC复合涂层腐蚀行为的影响

Effect of current density on the corrosion behavior of Ni-Co-P/SiC composite coatings prepared via ultrasonic pulse electrodeposition

  • 摘要: 为探究电流密度对超声脉冲电沉积纳米复合涂层耐腐蚀性能的影响,以不同电流密度在45钢表面制备了Ni-Co-P/SiC复合涂层,对涂层的微观形貌、物相结构、水接触角、腐蚀行为以及腐蚀后形貌进行了表征。结果表明:电流密度的改变导致涂层的表面形貌、物相结构等发生变化。随着电流密度的升高,涂层的SiC含量、水接触角、耐腐蚀性均呈现先升高后下降的趋势。在4 A·dm−2时,水接触角达到最大值105.2º,SiC含量达到最高值0.95at.%,EcorrIcorrRct分别达到最高值−0.446 V、最低值1.111 μA·cm−2以及最大值6565.1 Ω·cm2。涂层表面的腐蚀破坏形式主要为孔洞、裂痕与剥落。电化学测试结果表现更佳的涂层,在腐蚀后的表面形貌相对平整;在电流密度过低或者过高情况下制备的涂层,腐蚀后的表面产生了较为明显的缺陷。

     

    Abstract: To investigate the effect of current density on the corrosion resistance of ultrasonic pulse electrodeposited nanocomposite coatings, Ni-Co-P/SiC composite coatings were prepared on the surface of 45# steel at different current densities. The micromorphology, phase structure, water contact angle, corrosion behavior, and post-corrosion morphology of the coatings were characterized. The results showed that changes in current density led to changes in the surface morphology, SiC nanoparticle conent, and phase structure of the coatings. With the increase of current density, the SiC content, water contact angle, and corrosion resistance of the coatings all showed a trend of first increasing and then decreasing. At a current density of 4 A·dm−2, the water contact angle reached its maximum value of 105.2°, the SiC content reached the highest value of 0.95at.%, and Ecorr, Icorr, and Rct reached their highest value of −0.446 V, the lowest value of 1.111 μA·cm−2, and the maximum value of 6565.1 Ω·cm2, respectively. The main forms of corrosion damage on the coating surface were pits, cracks, and spalling. Coatings that performed better in electrochemical tests exhibited a relatively flat surface morphology after corrosion. Coatings prepared at either too low or too high current densities had more significant defects on the surface after corrosion.

     

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