GNPs强韧化B4C复合材料的制备及性能研究

Preparation and properties of GNPs strengthened and toughened B4C

  • 摘要: 以碳化硼(B4C)和石墨烯纳米片(GNPs)为原料,采用热压烧结工艺制备了GNPs/B4C复合材料。系统研究了分散工艺对GNPs结构的影响,以及GNPs含量和烧结温度对材料微观结构演变及力学性能的影响规律。通过时间-位移烧结曲线揭示了GNPs对致密化行为的作用机制。研究结果表明,超声分散有助于GNPs片层的有效剥离,不会造成结构损害。球磨工艺能够破碎GNPs团聚体,显著降低其尺寸和数量,从而提高其在B4C基体中的均匀分散性。复合材料的致密度随着温度的升高而提升,并在2000 ℃时接近全致密。当烧结温度为2000 ℃、压力为25 MPa时,GNPs添加量为4wt.%时,GNPs/B4C复合材料的致密度、维氏硬度、抗弯强度、断裂韧性分别为99.4%、30 GPa、433 MPa、5.13 MPa·m1/2。断裂面裂纹延展行为分析表明,裂纹偏转、分支、桥接和GNPs片层拔出等增韧机制在B4C基体中普遍存在,是材料断裂韧性提高的主要原因。

     

    Abstract: Graphene nanoplatelets/boron carbide(GNPs/B4C) composites were fabricated by hot-pressing with B4C and GNPs as raw materials. Thoroughly examines the impact of dispersion processes on the structure of GNPs. This study comprehensively investigates the effect of dispersion processes on the structural integrity of GNPs and systematically explores the influences of GNPs content and sintering temperature on microstructural evolution and mechanical performance. Furthermore, the role of GNPs in densification behavior was elucidated through the analysis of time-displacement sintering curves. The results reveal that ultrasonic dispersion promotes the exfoliation of GNP layers without inducing structural damage. Ball milling effectively disintegrates GNP agglomerates, significantly reducing both their size and quantity, thereby improving their uniform distribution within the B4C matrix. The density of the GNPs/B4C composite increases with rising temperature, approaching near-complete densification once the temperature reaches 2000℃. The relative density of the composites increases with the rise in sintering temperature, reaching near-full densification at 2000℃. At 2000℃ and 25 MPa, the B4C composite with 4wt.% GNPs exhibited the relative density of 99.4%, Vickers hardness of 30 GPa, flexural strength of 433 MPa, and fracture toughness of 5.13 MPa·m1/2. Analysis of the crack propagation behavior on the fracture surface indicates that toughening mechanisms such as crack deflection, branching, bridging, and the pull-out of GNPs are widely present in the B4C matrix. These mechanisms are the primary contributors to the improvement in the fracture toughness of the material.

     

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