改性纳米MgO/PLLA复合薄膜的制备及性能

Preparation and properties of modified MgO nanoparticles/PLLA composite films

  • 摘要: 为了改善左旋聚乳酸(PLLA)的降解性,采用溶液共混法将PLLA和MgO纳米颗粒(MgO-NPs)进行复合,制备了一种具有良好力学性能的骨修复复合材料.结果显示:改性MgO纳米颗粒(g-MgO-NPs)在PLLA基体中的分散效果及界面结合性比未改性的好.4%(质量比)g-MgO-NPs的添加量使薄膜的拉伸强度从10.6 MPa增大到30.1 MPa,断裂伸长率从71%减小为59%,并使薄膜降解后的pH值趋于稳定,基本接近生理盐水的pH值.由此表明:g-MgO-NPs在一定程度上能改善聚乳酸复合膜的降解性及其力学性能.

     

    Abstract: To improve the degradability of poly (L-lactic acid) (PLLA) and prepare the bone repair material with good mechanical properties, the composites consisting of PLLA and MgO nanoparticles (MgO-NPs) have been prepared. The result suggests that, compared with pure PLLA, modified MgO nanoparticles (g-MgO-NPs) significantly enhance its dispersion in PLLA matrix and its interfacial bonding with PLLA matrix. With addition of 4%(mass ratio) g-MgO-NPs, the tensile strength of film increases from 10.6 MPa to 30.1 MPa, and its elongation at break decreases from 71% to 59%. The pH of film tends to be a relatively stable value and be close to that of the physiological saline after degradation. It reveals that g-MgO-NPs improve the degradability and mechanical properties of polylactic acid composite films in a certain extent.

     

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