PZT陶瓷/橡胶复合材料的压电性能

PIEZOELECTRIC PROPERTIES OF PZT/RUBBER COMPOSITES

  • 摘要: 用PZT压电陶瓷粉末分散在无压电性的橡胶基体中制成压电复合材料。通过压电常数和介电常数测定、扫描电镜、介电谱等手段研究了有关因素对复合材料压电性能的影响。结果表明,复合材料的压电常数d33随PZT体积含量φ和橡胶介电常数ε1的增加而增大,随PZT介电常数ε2的增加而减小,符合理论式 d33=15φε1d33/(1-φ)(2+3φ)ε2 橡胶基体的极性基团、极性链节和交联健偶极的转向极化及分子链的柔性对复合材料的极化和压电常数有重要影响。橡胶的极性越大及分子链的柔性越高,则复合材料的压电常数d33越高。

     

    Abstract: The piezoelectric composites were prepared by PZT ceramic powders (inclusions) and synthetic rubbers(matrix).The effect of several factors on the piezoelectric properties of the composits was studied by measuring piezoelectric and dielectric constants, and using scanning electron microscope and dielectric spectroscopy.The results show that the piezoelectric constants d33 of the composites increase with the increasing of the PZT volume fraction φ,the dielectric constants ε1 of the rubbers and the piezoelectric constants d33 of PZT ceramics,and decrease with increasing dielectric constant ε2 of ceramics powders.The piezoelectric constants d33 of the composites can be expressed as d33=15φε1d33/(1-φ)(2+3φ)ε2.

     

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