差示扫描量热法研究不饱和聚酯固化反应

DSC ANALYSIS OF THE CURING REACTION OF UNSATURATED POLYESTER 3301

  • 摘要: 本文用国产CDR-1型差动热分析仪(简称DSC),采用恒温和动态两种方法,研究3301不饱和聚酯固化反应,得到恒温和动态下的热效应和固化工艺参数,并通过阿累尼乌斯方程和基辛格方程,分别求出恒温和动态固化反应的表观活化能E。

     

    Abstract: With isothermal and dynamic method,an analysis was made on the curing reaction of 250℃ high temperature strain gauge adhesive composed of unsaturated polyester 3301,styrcne,cyclohexanone peroxide and cobalt(Ⅱ) naphtheqnate by using CDR-1 differential scanning calorimeter.Thermal effect(ΔH) and curing parameters were obtained in isothermal and dynamic conditions. Apparent activity energy (ΔE) in isothermal and dynamic conditions were computed by using Arrhenius and Kissinger's equations. The results obtained from this work provided very important information for determining processing conditions of 250℃ high temperture stain gauae adhesive.

     

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