热塑性树脂增韧双马来酰亚胺树脂的研究
RESEARCH ON TOUGHENING BISMALEIMIDE RESIN WITH THERMOPLASTIC RESIN
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摘要: 本文讨论了用热塑性(TP)树脂聚砜(PSF)和聚醚砜(PES)增韧双马来酰亚胺(BMI)树脂的研究.实验表明,增韧后的树脂在150℃的粘度小于0.5(Pa·S),其复合材料的成形压力为0.3~0.7(MPa),固化温度为180℃,上述特性满足热压罐成形的工艺要求.树脂的预浸料具有较好的粘性和铺叠性,贮存期一个月以上(室温).树脂保持了较好的耐热性能,可在177℃长期使用.其复合材料的冲击强度明显提高,经聚砜增韧后提高了90%.PSF的增韧效果比PES明显.研究表明,只有当TP树脂含量不低于15%时,方可获得较明显的增韧效果.TP树脂是以球形颗粒分散于BMI基体中,这些颗粒起到了抑止微裂纹扩展的作用.Abstract: This paper deals with the toughening bismaleimide (BMI) resin with thermoplastic (TP) resin,Polysulfone an d Polyether sulfone.The experiment shows that the viscosity of toughened resira is 0.5(Pa·S)at 150℃, the forming pressure of their composites is between 0.3-0.7 (MPa),curing temperature is 180℃,all of the properties mentioned above can meet the technological requirement of autoclave forming. The prepregs impregnated with these resins have quite good tack and drape,the shelf-live is more than one month(at room, temperature).The toughened resins keep quite good heat resistence and can be used permanently at 177℃.The impact strength of their composites increases obviously and, being toughened with PSF,by a factor of 90%.The toughening effect of PSF is better than that of PES.