CF/PEEK复合材料界面层结构与性能关系研究
STUDIES ON INTERFACIAL STRUCTURE-PROPROPERTIES OF THE CARBON FIBER REINFORCED PEEK
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摘要: 本文根据聚醚醚酮(PEEK)在碳纤维表面形式的横晶层的结构特征分析,建立了CF/FEEK复合材料界面层微观力学性能的理论方程,计算了界面层的杨氏模量.通过超声浸渍法测量复合材料的力学性能验证了计算结果,证明所进行的分析合理.计算结果表明,PEEK界面横晶层在垂直于纤维方向的杨氏模量Er随PEEK结晶度的增大,或随横晶中PEEK晶片长度的增大而增大,并随晶片厚度的增大而减小.该界面层的上述模量值始终高于界面层附近球晶的模量值Es,两者之间的比值ET/Es;依赖于横晶及球晶中的晶片长度b、厚度c和宽度a.由于界面层的模量高于非界面层的模量,当复合材料中纤维表面形成横晶时,复合材料将有较高的刚性.Abstract: A mechanical model of the interfacial transcrystallinity in the composite of polyetheretherketone (PEEK) reinforced with carbon fiber was obtamed on the basis of its structural ch arateristic.Young's modulus of the transcrystallinity in the direction perpendicular to the fibre ov which it grows was found to be greater than that of the bulk opherulite,and depend on the lamellar structure in the transcrystallinity.It incre ases with the increasing of lamellzr length or thickness,but decrease;with the increasing of the lamellar width.The reason was discussed,and the result was verified with experiments.