碳纤维涂覆SiC新工艺及涂层纤维的力学特性
A NEW PROCESS FOR PRODUCING SiC COATING ON CARBON FIBRES AND THE MECHANICAL PROPERTIES OF SiC COATED FIBRES
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摘要: 用气相SiO和CO反应形成SiC的方法成功地在碳纤维上涂覆SiC.SiC涂层是由β-SiC团粒从碳纤维表面向外生长形成,并具有玉米棒子状的表面形貌。SiC层厚度增加到≥0.2μm,涂层纤维的拉伸强度随SiC层厚度增加而下降,此结果与Ochiai的理论模型相吻合。SiC层厚度达到1μm的涂层纤维,其拉伸时的力学行为与具有弱界面结合的1维脆性纤维-脆性基质复合材料相似,并显示SiC层的多次断裂。对碳纤维芯因涂层处理而引起的性能退化进行了讨论。Abstract: SiC coated fibres were obtained by a new method using SiO and CO to form SiC and deposit on to the carbon fibres. Columnar β-SiC grains grew radially out from the carbon fibre surface and formed a SiC coating with corncob-like surface morphology. When the thickness of the SiC coating increases to≥0.2pm, the tensile strength of the SiC coated fibre decreases with the increasing of thickness of SiC coating and this result is coincident with Ochiai' s theoretical model. For the fibres with lcm SiC coating, their mechanical behavior in tensile is similar to a 1 D brittle fibre-brittle matrix composite with weak fibre-matrix bonding and multiple fracture of SiC coating is shown. The degradation of the carbon fibre core caused by the coating process is discussed.