木质素基环氧树脂的研究进展

Progress of research in lignin-based epoxy resins

  • 摘要: 以石化产品为原材料合成环氧树脂将面临资源短缺和环境污染问题,利用环保可再生生物质材料制备环氧树脂越来越受到欢迎。木质素是仅次于纤维素的第二大天然非石油资源,具有可再生、无污染等优势,是替代石油资源的理想选择。然而,木质素具有独特的异质性和空间位阻,使得合成环氧树脂较为困难。通过化学改性能够克服这种问题,对于环氧树脂性能也有一定改善。本文综述了木质素环氧树脂最新的研究进展。首先,阐述了木质素的结构和特点。接着,重点讨论了木质素的酚化、胺化、羟甲基化等改性方式对其合成环氧树脂力学性能的影响。此外,探讨了木质素环氧树脂在电子封装与涂料、胶黏剂、碳纤维领域中的应用。最后,还总结了木质素基环氧树脂在制备工艺、性能优化等方面存在的一些问题,并对未来发展方向予以展望。

     

    Abstract: Synthesizing epoxy resins with petrochemical products as raw materials will face the problems of resource shortage and environmental pollution, and the use of environmentally friendly renewable biomass materials to prepare epoxy resins is becoming more and more popular. Lignin is the second largest natural non-petroleum resource after cellulose, with the advantages of renewable and non-polluting, which is an ideal choice to replace petroleum resources. However, lignin has unique heterogeneity and spatial site resistance, making it more difficult to synthesize epoxy resins. Chemical modification can overcome this problem and improve the performance of epoxy resins. This paper summarizes the latest research progress of lignin epoxy resins. First, the structure and characteristics of lignin are described. Then, the effects of the modifications of lignin, such as phenolization, amination, and hydroxymethylation, on the mechanical properties of its synthetic epoxy resins are focused. In addition, the applications of lignin epoxy resins in the fields of electronic encapsulation and coatings, adhesives, and carbon fibers are discussed. Finally, some problems in the preparation process and performance optimization of lignin-based epoxy resins are also summarized, and the future development direction is envisioned.

     

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