三维网络碳纳米管增强环氧树脂复合材料的细观力学
Microscopic mechanical behavior of reticulate carbon nanotube reinforced epoxy composites
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摘要: 根据网络碳纳米管/环氧树脂(Reticulate Carbon Nanotubes/Epoxy, R-CNTs/EP)复合材料的结构特点, 假设R-CNT均匀分布, 建立了R-CNT/EP复合材料的三维有限元模型。利用有限元法分析了R-CNT/EP复合材料单胞的细观变形, 用二尺度展开法计算了R-CNT/EP复合材料在不同应变下的有效刚度系数。分析结果表明: R-CNT/EP复合材料为各向异性材料, 沿蒸汽流动方向的强度远大于其他方向的强度, 且R-CNT的形状对R-CNT/EP复合材料的力学性能有显著影响, 各刚度系数以及杨氏模量在Y型接头处各角相等时最大; R-CNT的体积分数对R-CNT/EP复合材料的力学性能有显著影响, 各有效性能均随着R-CNT体积分数的增大而增大, 但是增大程度不同。Abstract: A three dimensional microscopic model of the reticulate carbon nanotube/epoxy (R-CNT/EP) composites was established according to its structural characteristics based on the assumption of the uniform distribution of R-CNT. The effective stiffness coefficients and Young's modulus of the R-CNT/EP composite were calculated by two-scale expansion method. It is shown that the mechanical properties of the R-CNT/EP composite are anisotropic and the strength along the direction of the vapor flow is much higher than that in other directions. The shape of the R-CNT plays an important role on the mechanical properties of the R-CNT/EP composite, and the effective stiffnesses and Young's modulus of the R-CNT/EP composites are the highest when the angles of the Y-junctions are equal. All of the effective stiffnesses and Young's modulus of the R-CNT/EP composites are enhanced with the increase of volume fraction of R-CNT, but the influence degrees are different.