C/SiC ZrC 复合材料在甲烷燃气环境中的氧化行为

Oxidation behaviors of C/SiC ZrC composites in a CH4 combustion gas environment

  • 摘要: 分别采用聚合物先驱体浸渗热解法(PIP)、浆料浸渗法(SI)结合PIP法和化学气相渗透法(CVI)制备了C/SiC复合材料, 利用化学气相沉积(CVD)工艺在三种C/SiC复合材料表面制备了ZrC涂层, 得到了C/SiC-ZrC复合材料。考核了三种C/SiC-ZrC复合材料在甲烷燃气环境中的氧化行为。结果表明: 在甲烷风洞中1800 ℃氧化30 min后, 前两种工艺制备的C/SiC-ZrC复合材料表面氧化严重, 氧化失重率均达到12%以上; CVI工艺制备的C/SiC-ZrC复合材料氧化失重率最小(6.9%), 抗氧化性能最好。

     

    Abstract: Three different C/SiC composites were fabricated by polymer infiltration and pyrolysis(PIP), slurry infiltration(SI) combined with PIP and chemical vapor infiltration(CVI). ZrC coatings were prepared by chemical vapor deposition(CVD) on C/SiC to form C/SiC-ZrC composites. The oxidation behaviors of the C/SiC-ZrC composites were investigated in a CH4 combustion gas environment. The results indicate that the surfaces of the C/SiC-ZrC composites fabricated by PIP and SI+PIP are severely oxidized with mass loss higher than 12% after oxidation at 1800 ℃ for 30 min. The C/SiC-ZrC composites fabricated by CVI exhibit the best oxidation resistance with a mass loss of 6.9%.

     

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