Preparation and properties of BAS glass-ceramics based anti-oxidation coatings
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摘要: 利用2层不同软化温度和不同热膨胀系数的BaO-Al2O3-SiO2(BAS)系微晶玻璃, 采用浆料涂覆—浸渍—多层共烧的方法制备了2种双层同组分和1种双层不同组分的Cf/SiC复合材料抗氧化涂层。3种结构的BAS系微晶玻璃涂层完整、 无明显缺陷, 涂层与Cf/SiC复合材料的结合状态良好, 有助于提高Cf/SiC复合材料的抗氧化性能。双层不同组分的BAS系微晶玻璃涂层在1200~1350 ℃范围内对提高Cf/SiC复合材料抗氧化性能的作用显著, 失重速率和失重量均明显减小。与未包覆涂层的复合材料相比, 包覆双层不同组分涂层的复合材料经历600次(每次保温10 min)热冲击后的失重降低了1/2~2/3, 保留的强度提高了7~15倍。Abstract: Two kinds of BaO-Al2O3-SiO2 (BAS) glass-ceramics with different soften points and thermal expansion coefficients were employed to prepare three kinds of gradient coatings for carbon fiber reinforced silicon carbide(Cf/SiC) composite. These coatings were fabricated with slurry deposition combined dipping method and multi-co-firing technology. These BAS glass-ceramics based coatings were integrated and defect-free. The coatings and the composites bind tightly, which can improve the anti-oxidation performance of the coated Cf/SiC composite. All coating systems can protect Cf/SiC composite from oxidation. The graded coatings protect Cf/SiC composite markedly, and the mass loss rate and mass loss of coated composites are reduced greatly within 1200~1350 ℃. Compared with uncoated composite, the mass loss of the coated composite is reduced by 1/2~2/3, and the reminant bending strength is enhanced 7~15 times after 600 thermal shock cycles in the experimental range.
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Keywords:
- composites /
- Cf/SiC /
- anti-oxidation coating /
- glass-ceramics /
- celsian
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