纳米SiO2 对双酚A环氧树脂电子束固化特性的影响

EFFECT OF NANO-SiO2 ON ELECTRON BEAM CURING CHARACTERISTICSOF BISPHENOL A EPOXY RESIN SYSTEM

  • 摘要: 探讨了电子束固化纳米SiO2 / 双酚A 环氧树脂复合材料体系的温度、固化度、固化区域的尺寸和动态力学性能随纳米粒子含量的变化规律, 研究了纳米SiO2 对体系电子束辐射固化特性的影响。结果表明, 随着纳米粒子含量的增加, 体系的放热峰逐渐降低; 少量纳米粒子的加入有助于增大试样固化区域的尺寸、提高固化度、玻璃化转变温度和高温模量; 纳米SiO2 的加入改变了电子束的传播途径, 但其电子束固化生长机制与未加入纳米粒子的纯树脂体系相似。

     

    Abstract: NANO-SiO2 particles were added in the bisphenol A epoxy resin. The curing characteristics of the NANO-SiO2 / epoxy resin system were researched. The effect s of NANO-SiO2 content on reaction temperature , gel fraction ,dimension of the cured area and dynamic mechanic performance of the elect ron beam ( EB) cured epoxy resin systemwere investigated. The result s show that the exothermal peak of the curing system decreases with the increasing ofNANO-SiO2 content , and a small amount of NANO-SiO2 particles cont ribute to increasing the dimension of the curedarea , gel f raction , glass temperature and high temperature modulus. The growth mechanism of the system withNANO-SiO2 particles is similar to that without NANO-SiO2 particles , although the propagation path of EB is changed byNANO-SiO2 particles.

     

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