Al N粉末特性对Al N-BN复合陶瓷致密化的影响

Influence of AIN powder characteristic on densif icationof AlN-BN composite ceramics

  • 摘要: 以比表面积分别为4. 26 和17. 4 m2 / g 两种AlN 粉末为原料, 添加5 %Y2O3 作为烧结助剂制备AlN15BN 陶瓷(质量分数, %) , 研究了AlN 粉末特性对复合陶瓷致密化过程的影响。结果表明, AlN 粉末比表面积对复合陶瓷致密化有重要影响, 比表面积高的AlN 粉末所制备的复合陶瓷致密化过程主要发生在1500~1650 ℃,1650 ℃烧结3 h 后, 复合材料的相对密度达95. 6 % , 继续升高温度, 对材料的密度影响不大; 而低比表面积的AlN 粉末所制备的复合陶瓷的致密化过程主要发生在1650~1850 ℃, 1850 ℃烧结3 h , 复合陶瓷的相对密度为86. 4 %。即高比表面积的AlN 粉末有利于获得相对密度高的AlN2BN 复合材料。

     

    Abstract: AlN-15BN (mass f raction , %) composite ceramics were fabricated with two different kinds of AlN powders with specific surface areas of 4. 26 m2 / g and a 17. 4 m2 / g , respectively , and 5 %Y2O3 as sintering additives.The effect s of the specific surface area of AlN powders on the densification of AlN-BN composite ceramics werestudied. The result s show that the specific surface area of AlN powders has great influence on the densificationprocess of composite ceramics. The densification temperature of composite ceramics is at 1500~1650 ℃with highspecific surface area AlN powder , and AlN-BN ceramics with relative density 95. 6 % was obtained af ter sintering at1650 ℃for 3 h. The density of this composite does not increase with the further increasing of sintering temperature.For AlN-BN ceramics prepared with low specific surface area AlN powders , the densification temperature is in therange of 1600~1850 ℃, and AlN-BN ceramics with relative density 86. 4 % was obtained af ter sintering at 1850 ℃for3 h. The high specific surface area of AlN powders can enhance the densification of AlN -BN composite ceramics.

     

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