纳米碳管/ 羟基磷灰石复合材料的凝胶注模

Gel-casting process of carbon nanotubes/ hydroxyapatite composite materials

  • 摘要: 采用凝胶浇注成型工艺制备了纳米碳管/ 羟基磷灰石复合材料坯体。研究了p H 值、分散剂、固相含量(纳米碳管和羟基磷灰石在料浆中的质量分数) 、分散工艺等因素对料浆和复合材料坯体性能的影响, 对坯体的力学性能进行了测试, 借助扫描电镜分析了坯体的微观组织。实验发现, 料浆的p H 值应控制在10~12 的范围内;聚甲基丙烯酸铵的浓度为0. 6 %时, 羟基磷灰石悬浮体流动性最好; 十二烷基磺酸钠的浓度在SDS/ CNTs = 1 %~2 %时, 纳米碳管/ 羟基磷灰石复相料浆的粘度最低; 采用球磨法制备的复相料浆固相含量达到55 % , 复合材料坯体的抗弯强度达到57. 403 MPa 。

     

    Abstract: The green bodies of carbon nanotubes/ hydroxyapatite (CNTs/ HA) composite were prepared by gel casting process. The effect s of p H , dispersant , content of solid in slurry and the dispersing process on the slurryand the properties of the green bodies were researched. The mechanical properties were tested , and the microst ructure was analysed using SEM. It is found that the p H value of the slurry should be cont rolled in the range 10 to 12.The fluidness of HA slurry is the best as the concent ration of NH4- PMAA is 0. 6 %. The viscosity of CNTs/ HAslurry reaches the lowest value as the concent ration of sodium dodecanesulphonate which is called SDS for shortchanges f rom SDS/ CNTs = 1 % to SDS/ CNTs = 2 %. The content of solid in CNTs/ HA slurry reaches 55 % and thebending st rength of the green bodies of CNTs/ HA composite reaches 57. 403 MPa by a ball mill process.

     

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