SPS原位制备(Ti,V)C/TiC增强铁基复合材料的显微组织、力学性能及磨损行为

Microstructure, mechanical properties and wear behavior of (Ti,V)C/TiC reinforced Fe-based composite materials in-situ fabricated by SPS

  • 摘要: 为了解决目前传统铸造法制备的陶瓷颗粒增强铁基复合材料存在的致密度较低、工艺可控性较差等问题,本文采用放电等离子烧结(SPS)技术,通过原位合成法在高铬铁基体中引入(Ti,V)C/TiC碳化物增强相,系统研究了(Ti,V)C/TiC增强铁基复合材料的微观组织、力学性能及磨损行为。通过优化烧结工艺(1050℃×30 min),成功制备了致密度高、界面结合良好的复合材料。结果表明,(Ti,V)C呈球状弥散分布,在界面处存在Cr元素富集的M7C3型碳化物过渡层,增强相之间存在高密度位错、晶体结构匹配良好。陶瓷颗粒增强区域硬度达1573.5 HV,TiC和(Ti,V)C的弹性模量(分别为443.13 GPa和396.01 GPa)显著高于基体相(244.62 GPa)。三体磨料磨损试验表明,复合材料具有优异耐磨性能,其体积损失仅为高铬铁基体的1/3,这归因于(Ti,V)C/TiC碳化物增强相的“阴影效应”以及高弹性模量对裂纹扩展的抑制作用,其磨损机制以微犁沟为主。本研究成果可为SPS技术制备高硬耐磨铁基复合材料提供理论参考和应用借鉴。

     

    Abstract: To address the problems of relatively low densification and poor process controllability in ceramic particle-reinforced iron-based composites prepared by conventional casting method, (Ti,V)C/TiC carbide reinforced high-chromium iron was in situ synthesized via spark plasma sintering (SPS) in this work. The microstructure, mechanical properties and wear behavior of the composites were systematically investigated. By optimizing sintering parameters (1050℃×30 min), high-density composites with strong interfacial bonding were successfully fabricated. The results show that (Ti, V)C particles are spherical and uniformly dispersed, accompanied by a Cr-enriched M7C3-type carbide transition layer at the interface. High-density dislocations and favorable crystallographic matching are present among the reinforcing phases. The ceramic particle reinforced zone exhibits a hardness of 1573.5 HV, with elastic moduli of TiC (443.13 GPa) and (Ti,V)C (396.01 GPa) significantly exceeding that of the matrix phase (244.62 GPa). Three-body abrasive wear tests indicate that the composites possess superior wear resistance, with only one-third the volume loss of pure high-chromium iron. This improvement can be attributed to the "shadow effect" of (Ti,V)C/TiC reinforcements and the suppression of crack propagation due to their high elastic modulus. The dominant wear mechanism is characterized by shallow ploughing grooves. This work can provide a theoretical and practical reference for fabricating high-hardness and wear-resistant Fe-based composites via SPS.

     

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