基于Zn-MOFs单前驱体一步碳化制备氮掺杂碳包覆硫化锌及其储钠性能研究

Facile one-step preparation of Nitrogen-doped carbon-coated zinc sulfide from only one Zn-MOFs precursor and its sodium storage performance

  • 摘要: 硫化锌凭借高理论容量和优异氧化还原可逆性成为钠离子电池理想负极材料,但其体积膨胀和多硫化物穿梭效应严重制约应用。常用碳包覆策略抑制体积膨胀,但传统方法存在制备工艺复杂(难以规模化)、需引入大量硫/氮源导致环境污染等瓶颈。通过简单廉价的方法合成了含硫元素的金属锌有机框架(Zn-MOFs)前驱体,经一步煅烧制备氮掺杂碳包覆硫化锌(ZSNC)。所制备的ZSNC有着形貌的可调控性、有效抑制活性颗粒团聚、暴露更多反应界面、更低的比表面积、更小的电荷转移电阻和更高的钠扩散系数。在钠离子电池中ZSNC表现出高可逆容量(100 mA/g下554.28 mAh/g)以及优异的倍率性能(1000 mA/g下296.22 mAh/g),在100 mA/g 经100次循环后容量保持率为81.24%的优异循环稳定性。该方法制备的ZSNC结构完整、高比容量、良好的倍率性能和循环稳定性,使其成为一种制备金属硫化物做电池负极的有效改善措施。

     

    Abstract: Zinc sulfide has become an ideal anode material for sodium-ion batteries due to its high theoretical capacity and excellent redox reversibility, but its volume expansion and polysulfide shuttling effect have severely restricted its application. Carbon capping strategy is commonly used to inhibit the volume expansion, but the traditional method has bottlenecks such as complicated preparation process (difficult to scale up) and environmental pollution due to the introduction of a large number of sulfur/nitrogen sources. Zinc metal-organic frameworks (Zn-MOFs) precursors containing sulfur elements were synthesized by a simple and inexpensive method, and nitrogen-doped carbon-coated zinc sulphone (ZSNC) was prepared by one-step calcination. The prepared ZSNC has tunable morphology, effective inhibition of active particle agglomeration, exposure of more reactive interfaces, lower specific surface area, smaller charge transfer resistance and higher sodium diffusion coefficient. The ZSNC exhibited high reversible capacity (554.28 mAh/g at 100 mA/g) as well as excellent multiplicative performance (296.22 mAh/g at 1000 mA/g) in sodium-ion batteries, and excellent cycling stability with 81.24% capacity retention at 100 mA/g after 100 cycles. The structural integrity, high specific capacity, good multiplicity performance and cycling stability of ZSNC prepared by this method make it an effective improvement for the preparation of metal sulfides as battery anodes.

     

/

返回文章
返回