B4C-SiC复合陶瓷力学性能的研究进展

Advance in investigation on mechanical properties of B4C-SiC composite ceramics

  • 摘要: B4C-SiC复合陶瓷结合了碳化硼(B4C)和碳化硅(SiC)的性能,具有良好的物理和力学性能。与单相B4C陶瓷相比,B4C-SiC复合陶瓷具有更高的断裂韧性;与单相SiC陶瓷相比,B4C-SiC复合陶瓷具有更大的硬度。B4C-SiC复合陶瓷有望替代单相B4C陶瓷和单相SiC陶瓷广泛应用于工程领域。B4C-SiC复合陶瓷的力学性能与B4C-SiC复合粉体的颗粒分散均匀性有关。同时,B4C-SiC复合陶瓷的力学性能还受微观结构和相组成的影响。为了降低B4C-SiC复合陶瓷的烧结温度,常在原料中添加烧结助剂,常用的烧结助剂主要有碳、氧化物、硼化物、碳化物、金属单质、非金属单质(除碳外)。不同烧结助剂促进B4C-SiC复合陶瓷烧结的机制各不相同;同时,这些烧结助剂通过影响B4C-SiC复合陶瓷的微观结构进而影响其力学性能。本文根据B4C-SiC复合陶瓷力学性能的研究结果,从B4C-SiC复合粉体、微观结构、相组成和烧结助剂等方面详细阐述了B4C-SiC复合陶瓷力学性能的影响因素,以期为B4C-SiC复合陶瓷的设计和研究提供依据。

     

    Abstract: B4C-SiC composite ceramics combine the properties of boron carbide (B4C) and silicon carbide (SiC) and have good physical and mechanical properties. Compared with monolithic B4C ceramics, B4C-SiC composite ceramics have improved fracture toughness. Compared with monolithic SiC ceramics, B4C-SiC composite ceramics possess increased hardness. B4C-SiC composite ceramics are expected to replace monolithic B4C ceramics and monolithic SiC ceramics to be widely used in engineering fields. The mechanical properties of B4C-SiC composite ceramics are related to the particle dispersion uniformity of B4C-SiC composite powders. Meanwhile, the mechanical properties of B4C-SiC composite ceramics are also influenced by their microstructure and phase composition. In order to reduce the sintering temperature of B4C-SiC composite ceramics, sintering additives are often added to the raw materials. The commonly used sintering additives include carbon, oxides, borides, carbides, metallic elements, and non-metallic elements (excluding carbon). The mechanisms by which different sintering additives promote the sintering of B4C-SiC composite ceramics vary. At the same time, these sintering additives affect the microstructure of B4C-SiC composite ceramics, which in turn affects their mechanical properties. Based on the research results of mechanical properties of B4C-SiC composite ceramics in recent years, the influencing factors of mechanical properties of B4C-SiC composite ceramics are summarized in this review from the aspects of B4C-SiC composite powders, microstructure, phase composition, and sintering additives, so as to provide a basis for the design and investigation of B4C-SiC composite ceramics.

     

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