EP-PDMS-PVDF-SiO2超疏水复合涂层的制备与耐摩擦性能

Preparation and abrasion resistance properties of EP-PDMS-PVDF-SiO2 superhydrophobic composite coating

  • 摘要: 提高超疏水涂层砂纸耐摩擦性能对其应用具有重要意义。因此,以环氧树脂(EP)、聚二甲基硅氧烷(PDMS)和聚偏氟乙烯(PVDF)为粘结剂,以4种纳米级二氧化硅(SiO2)粒子为主要填料和一种微米级SiO2粒子作为增强涂层耐摩擦性能的辅助填料制备了一种耐摩擦性能优异的超疏水涂层,并对其砂纸耐摩擦性能进行系统地测试和分析。接触角测试结果表明涂层水滴接触角和滚动角分别保持在156°~165°和2°~4°之间。砂纸摩擦测试表明添加2 μm或5 μm的SiO2粒子能使涂层耐摩擦周期提高2~3倍。同时,涂层耐摩擦性能还与砂纸粒度相关。涂层被9 μm或6.5 μm粒度砂纸摩擦失去超疏水性能后,能通过19 μm或11 μm粒度砂纸的摩擦而恢复其超疏水特性。然而,涂层被38、19或11 μm粒度砂纸摩擦后其超疏水性能无法恢复。分析表明,低粒度砂纸更易破坏涂层表面多级微纳粗糙结构,但该结构可通过高粒度砂纸摩擦而被恢复,高粒度砂纸则倾向于使涂层从基材表面剥离。

     

    Abstract: Improving the sandpaper abrasion resistance of superhydrophobic coating is of great significance for its application. Therefore, a superhydrophobic coating with exceptional abrasion resistance was prepared by utilizing epoxy resin (EP), polydimethylsiloxane (PDMS) and polyvinylidene fluoride (PVDF) as binders in combination with four types of nano-sized silicon dioxide (SiO2) particles as primary fillers. Moreover, micron-sized SiO2 particles are incorporated as auxiliary fillers to enhance the abrasion resistance of the coating. In this work, the sandpper abrasion resistance of the coating is systematically tested and analyzed. The results of the contact angle test demonstrate that the contact angle and rolling angle of water droplets on the coating surface remain within the range of 156°-165° and 2°-4°, respectively. Sandpaper abrasion tests reveal that 2 μm or 5 μm SiO2 particles can enhance the sandpaper abrasion-resistance cycles of the coating by 2-3 times. Additionally, it is observed that the grit of sandpaper also affects the abrasion resistance of the coating. If the coating loses its superhydrophobic properties due to abrasion with 9 μm or 6.5 μm grit sandpaper, these properties can be restored by the abrasion of 19 μm or 11 μm grit sandpaper. However, if the coating was abraded by 38, 19 or 11 μm grit sandpaper, the superhydrophobic properties cannot be restored with abrasion of any grit sandpaper. The result analysis shows that small grit sandpapers are more likely to damage the hierarchical micro-nano structure on the surface of the coating. However, this structure can be recovered through the abrasion of large grit sandpapers. Meanwhile, the sandpaper with large grit tends to induce the coating to peel off from the substrate surface.

     

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