铁氧体/芦苇秆炭复合材料的制备与吸波性能

Preparation and microwave absorption properties of ferrite/reed charcoal composites

  • 摘要: 为了解决铁氧体吸波材料密度大、吸收带宽窄等问题,以芦苇茎秆为原料,采用常温浸渍及高温原位生长法制备了铁氧体/芦苇秆炭(Ferrite/RC,FRC)复合材料,通过调节碳化温度调控复合材料的电磁特性和电磁波吸收性能。SEM、TEM、XRD、VSM及VNA等结果表明:Ferrite/RC复合材料保留了芦苇秆天然的三维蜂窝状网络结构,Fe3O4及铁纳米颗粒均匀分布在芦苇秆碳壁与孔道中;提升碳化温度(650~690℃)可增大复合材料的电导率与介电损耗能力,但温度过高会导致材料阻抗失配从而降低电磁衰减能力。碳化温度为670℃时制备的复合材料(FRC-670)吸波性能最佳,它在匹配厚度仅为1.7 mm时反射损耗达到−45.7 dB,对应有效吸收带宽为3.4 GHz;在厚度为2 mm时有效吸收带宽为5.7 GHz (12.1~17.8 GHz)。其主要的电磁波衰减机制源于复合材料良好的电导损耗、极化弛豫损耗以及电损耗与磁损耗的协同作用。铁氧体/芦苇秆炭复合材料优异的吸波性能在电磁波吸收领域具有良好前景,可促进芦苇资源的高值化与功能化应用。

     

    Abstract: In order to solve the problems of high density and narrow absorption bandwidth of ferrite absorbing materials, the ferrite/reed charcoal (Ferrite/RC, FRC) composites were prepared from reed stalks by impregnation and high temperature in-situ growth methods. The electromagnetic characteristics and electromagnetic wave absorption properties of the composites were controlled by tailoring the carbonization temperature. The results of SEM, TEM, XRD, VSM and VNA show that the Ferrite/RC composites retain the natural three-dimensional honeycomb network structures of the reed stalks, and Fe3O4 and iron nanoparticles are uniformly distributed in the charcoal wall and pores of the reed stem; Raising the carbonization temperature (650-690℃) can increase the conductivity and dielectric loss ability of composites, but excessive temperature can lead to impedance mismatch of the material and reduce its electromagnetic attenuation ability. The composites prepared at a carbonization temperature of 670℃ exhibit the best absorption performance, with a reflection loss of −45.7 dB at a thickness of only 1.7 mm and an effective absorption bandwidth of 5.7 GHz (12.1-17.8 GHz) at a thickness of 2 mm, which is attributed to the good conductivity loss, polarization relaxation, and the synergistic effect of electrical and magnetic losses of composite materials. The excellent absorption performance of Ferrite/RC composites has good prospects in the field of electromagnetic wave absorption, which can promote the high-value and functional application of reed resources.

     

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