铝离子电池正极材料研究进展

Research progress of cathode materials for aluminum-ion batteries

  • 摘要: 铝离子电池具有高理论比容量、安全性高、低成本、原料来源充足等优势,被认为是锂离子电池的潜在替代品。但正极材料固有特性的不足极大地限制了铝离子电池的进一步发展。本文总结了正极材料在铝离子电池应用领域所发挥的重要作用,综述了铝离子电池正极材料的作用机制和研究进展,概述了碳基、过渡金属氧化物、硫化物、有机材料、金属有机骨架化合物等正极材料对铝离子电池电化学性能的影响。最后,对正极材料在铝离子电池领域亟需解决的问题进行了探讨,对未来铝离子电池正极材料的发展方向提出了展望。

     

    Abstract: With high theoretical specific capacity, high safety, low cost, and sufficient raw material sources, aluminum-ion batteries have been regarded as potential alternatives to lithium-ion batteries. However, the shortcomings of the inherent characteristics of the cathode material have greatly limited the further development of aluminum-ion batteries. In this paper, the important role of cathode materials in the application filed of aluminum ion battery was summarized, the mechanism of action and research progress of aluminum ion electrode materials were reviewed, and the effects of various cathode materials such as carbon-based, transition metal oxides and sulfides, organic materials and metal-organic skeletal compounds on the electrochemical performance of aluminum ion batteries were summarize. Finally, the problems that need to be solved urgently in the field of positive electrode materials for aluminum ion batteries are discussed, and the future development direction of positive electrode materials for aluminum ion batteries is proposed.

     

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