润滑-增强双功能微胶囊增强UHMWPE材料

Lubrication-reinforcement microcapsules reinforce UHMWPE material

  • 摘要: 采用碳酸氢钠和水合硫酸铝溶液原位聚合制备了以聚四氟乙烯 (PTFE) 为核材、Al(OH)3为壳材的润滑-增强双功能微胶囊PTFE@Al(OH)3。将其表面用乙烯基三甲氧基硅烷 (VTMS) 处理后作为超高分子量聚乙烯 (UHMWPE) 的增强填料,混合均匀后,用放电等离子烧结 (SPS) 加工为复合材料。采用SEM、TEM、FTIR、UMT-5多功能摩擦磨损试验机、三维白光干涉仪、拉伸压缩试验机等方法分别对微胶囊在基体中的分散性能、复合材料的摩擦学性能和力学性能进行了表征。实验结果表明:微胶囊的加入提高了复合材料的摩擦学性能 (摩擦系数降低35%,磨损量降低20%) 和力学性能 (压缩强度变为原来的2.5倍),同时微胶囊具有较好的分散性。

     

    Abstract: Lubrication-reinforcement bifunctional microcapsules PTFE@Al(OH)3 using polytetrafluoroethylene (PTFE) as the core material and Al(OH)3 as the shell material were prepared by in-situ polymerization of sodium bicarbonate and aluminum sulfate solutions. Its surface was treated with vinyl trimethoxysilane (VTMS) and used as a reinforcing filler for ultra-high molecular weight polyethylene (UHMWPE). After it was evenly mixed, processed into composite materials using spark plasma sintering (SPS). The dispersion properties of microcapsules in the matrix, tribological properties and mechanical properties of composite materials were characterized by SEM, TEM, FTIR, universal micro tribometer (UMT-5), three-dimensional white light interferometer and methods of tensile compression testing machine. It is demonstrated that the addition of microcapsules effectively improve the tribological properties (friction coefficient decreased by 35%, wear amount decreased by 20%) and mechanical properties (compression strength increased by 2.5 times) of the composites. In addition, the dispersibility of the microcapsules is also greatly improved by surface modification.

     

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