基于电泳沉积法的Ti3C2Tx MXene改性国产高模高强碳纤维

Ti3C2Tx MXene-modified domestic high-modulus high-strength carbon fibers based on electrophoretic deposition method

  • 摘要: 为提升国产高模高强碳纤维的表面特性及其复合材料的界面性能,采用连续化电泳沉积工艺,在国产高模高强碳纤维(BHM5碳纤维)表面构筑Ti3C2Tx MXene纳米片层。通过SEM、XPS、动态接触角、INSTRON万能材料试验机对改性前、后BHM5碳纤维的表面形态、表面元素含量、表面润湿性及其复合材料的力学性能和断面形貌进行了表征,探讨了Ti3C2Tx MXene改性BHM5碳纤维复合材料的界面增强机制。结果表明:经Ti3C2Tx MXene改性后的BHM5碳纤维表面粗糙度和比表面积增加,具备了与环氧树脂基体良好的机械互锁能力。碳纤维表面极性基团的含量明显上升,表面润湿性得以增强。在15 V电压下对BHM5碳纤维处理2 min后,其复合材料的层间剪切强度达到82.54 MPa,相较于未处理的碳纤维制成的复合材料,提升了28.2%。

     

    Abstract: In order to improve the surface properties of domestic high-modulus high-strength carbon fibers and the interfacial properties of their composites, Ti3C2Tx MXene nanosheets were constructed on the surface of domestic high-modulus high-strength carbon fibers (BHM5 carbon fibers) using a continuous electrophoretic deposition process. The surface morphology, surface element content, surface wettability of BHM5 carbon fibers and the mechanical properties and cross-section morphology of their composites before and after modification were characterized by SEM, XPS, dynamic contact angle, and INSTRON universal material tester, and the interfacial enhancement mechanism of the Ti3C2Tx MXene-modified BHM5 carbon fiber composites was investigated. The results show that the surface roughness and specific surface area of the Ti3C2Tx MXene-modified BHM5 carbon fibers increase, possessing a good mechanical interlocking ability with the epoxy resin matrix. The content of polar groups on the surface of the carbon fiber increases significantly, and the surface wettability is enhanced. After treating the BHM5 carbon fibers at 15 V for 2 min, the interlaminar shear strength of the composites reaches 82.54 MPa, which is enhanced by 28.2% compared with the composites made of untreated carbon fibers.

     

/

返回文章
返回