双交联废弃瓦楞纸基气凝胶缓冲材料的制备与性能

Preparation and properties of double crosslinked waste corrugated paper-based aerogel buffer materials

  • 摘要: 以废弃瓦楞纸(WCP)为原料,明胶(G)和植酸(PA)为改性剂,采用溶胶-凝胶法制备高吸能气凝胶。对明胶用量、植酸用量和反应温度对双交联改性废纸基气凝胶力学性能的影响进行了研究,并通过SEM、FTIR、XRD和TGA表征了明胶单一改性和明胶-植酸双交联改性前后气凝胶的结构与性能变化。结果表明:改性单体成功交联到废纸纤维上,双交联改性后的废纸基气凝胶呈现三维网状结构,相较于未改性和单一改性废纸基气凝胶具有较高的热稳定性、优异的隔热性能(0.045 W·m−1·K−1)和超强的吸能性(应变70%时,单位体积吸收能为253.45 kJ/m3),吸能性分别为珍珠棉(EPE)和乙烯-醋酸乙烯酯共聚物(EVA)的11.26和2.7倍。作为包装运输过程中的一种绿色缓冲材料,具有广阔的应用前景。

     

    Abstract: Waste corrugated paper (WCP) was used as raw material, gelatin (G) and phytic acid (PA) were used as modifiers, and high energy absorption aerogel was prepared by sol-gel method. The effects of G dosage, PA dosage, and reaction temperature on the mechanical properties of dual-crosslinked modified waste paper-based aerogels were investigated. The structural and performance changes of aerogels before and after single modification with G and dual modification with G and PA were characterized by SEM, FTIR, XRD and TGA. The results show that the modified monomer is successfully crosslinked onto the waste paper fiber, and the double crosslinked waste paper based aerogel presents a three-dimensional network structure. Compared with the unmodified and single modified waste paper based aerogel, it has higher thermal stability, excellent thermal insulation (0.045 W·m−1·K−1) and super energy absorption (Absorption energy per unit volume is 253.45 kJ/m3 at 70% strain). The energy absorption capacity is 11.26 and 2.7 times higher than that of expanded polyethylene (EPE) and ethylene vinyl acetate (EVA), respectively. As a green cushioning material in the packaging and transportation process, it has broad application prospects.

     

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