基于大面积全无机钙钛矿太阳电池研究进展

Research progress on large-area all-inorganic perovskite solar cells

  • 摘要: 近年,全无机钙钛矿太阳电池因其具有优良的光电性能及优异的热稳定性成为光伏领域的关注热点之一。该类电池现获得了21.15%的光电转换效率(PCE),并且还有望得到进一步地提高。然而,目前获得高效率全无机钙钛矿电池的有效面积都相对较小,多数处于0.1 cm2水平,大面积全无机钙钛矿太阳电池的PCE会因有效面积的增加而大幅降低。而大面积电池的制备对于全无机钙钛矿太阳电池的商业化应用极其重要。为了让全无机钙钛矿类材料在光伏领域上得到更好地应用,对全无机钙钛矿构建多组分复合材料结构及制备工艺调整是最简单而有效的方法。本文针对目前大面积全无机钙钛矿太阳电池进行系统综述,对较大面积的全无机钙钛矿太阳电池已取得的成果进行总结。针对目前大面积全无机钙钛矿太阳电池所处现状进行分析,并且对可制备大面积钙钛矿太阳电池的工艺及电池性能优化策略进行了系统性的归纳,最后对其领域未来发展趋势进行了展望。

     

    Abstract: In recent years, all-inorganic perovskite solar cells have become a hot topic in the photovoltaic field due to their excellent optoelectronic properties and outstanding thermal stability. This type of cell has achieved a photovoltaic conversion efficiency (PCE) of 21.15%, and further improvements are expected. However, the effective area of currently efficient all-inorganic perovskite cells is relatively small, mostly around 0.1 cm2, and the PCE of large-area all-inorganic perovskite solar cells will decrease significantly with an increase in effective area. The preparation of large-area cells is crucial for the commercial application of all-inorganic perovskite solar cells. In order to make all-inorganic perovskite materials better apply in the photovoltaic field, it is the simplest and most effective method to construct a multi-component composite structure and adjust the preparation process of all-inorganic perovskite. This article provides a systematic review of the progress in large-area all-inorganic perovskite solar cells, summarizing the achievements of all-inorganic perovskite solar cells with larger area. An analysis of the current status of large-area all-inorganic perovskite solar cells is also presented, and systematic summaries are given for the process of preparing large-area perovskite solar cells and strategies for optimizing cell performance. Finally, the future development trends in this field are discussed.

     

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