MOFs/生物质基复合材料及其应用进展

MOFs/biomass matrix composites and their application progress

  • 摘要: 金属有机框架(MOFs)因其具有比表面积大、孔隙度和孔径可调、表面修饰功能强、化学和热稳定性好等优点而被广泛应用于材料领域。然而,MOFs容易团聚,其固有的晶体结构导致其柔韧性、加工性和可回收性较差,严重限制了其应用。近年来,MOFs与环保可再生的生物质材料复合,不仅解决了上述问题,且兼有生物质和MOFs两种材料的优势,实现了其在新兴领域的应用。从不同生物质原料出发,介绍了MOFs/生物质基复合材料的种类、制备方法,详细综述了该材料在水体净化、气体分离、抗菌处理、电化学应用方面的研究进展,并针对制备和应用过程中存在的问题提出了建设性的意见,为研究者设计和开发高性能MOFs/生物质复合材料提供科学的依据。

     

    Abstract: Metal-organic frameworks (MOFs) are widely used in materials because of their large specific surface area, adjustable porosity and pore size, strong surface modification function, and good chemical and thermal stability. However, MOFs are prone to agglomeration, and their inherent crystal structure leads to poor flexibility, processability and recyclability, which severely limits their application. In recent years, MOFs have been compounded with environmentally friendly and renewable biomass materials, which not only solves the above problems, but also combines the advantages of biomass and MOFs to realize their application in emerging fields. Starting from different biomass raw materials, this paper introduces the types and preparation methods of MOFs/biomass matrix composites, reviews the research progress of MOFs/biomass matrix composites in water purification, gas separation, antibacterial treatment and electrochemical application in detail, and puts forward constructive suggestions for the problems existing in the preparation and application process, in order to provide a scientific basis for researchers to design and develop high-performance MOFs/biomass composites.

     

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