十四酸改性SiO2/超支化PDMS自修复涂层的制备及其超疏水性能

Preparation of myristic acid modified SiO2/hyperbranched-PDMS self-healing coating and its superhydrophobic performance

  • 摘要: 为了提高超疏水涂层的耐久性,通过设计“基底-黏性自修复聚合物-疏水粒子”自下而上的涂层体系,制备了具有自修复功能的超疏水表面:以含有丰富氢键的超支化聚硅氧烷(HB-PDMS)作为黏性自修复聚合物,通过十四酸(MA)对纳米SiO2进行疏水改性作为疏水粒子以构筑表面粗糙结构。探究了SiO2改性的最佳工艺:当MA与SiO2质量比为1∶1,改性时间为3 h时,所制备的超疏水涂层接触角为152.61°,滚动角为1.9°,具有优异的防污性能。涂层经受刀片划伤后通过简单热处理即可修复划痕,自修复性能优异。与纯铝相比,该复合涂层具有良好的防腐性能,缓蚀效率可达87.53%。此外,经历5次胶带剥离、磨损长度为30 cm的线性耐磨测试、50 min的超声振荡测试、10次温差循环和24 h紫外照射后,接触角依旧保持在150°以上,说明该涂层具有良好的耐候性和机械稳定性。该研究为自修复超疏水涂层的制备提供了新策略,有望应用于建筑防污领域。

     

    Abstract: In order to improve the durability of superhydrophobic coatings, in this work, we designed a bottom-up coating system of “substrate-viscous self-healing polymer-hydrophobic particle”, thereby the superhydrophobic surface with self-healing function was successfully fabricated: Hyperbranched polydimethylsiloxane (HB-PDMS) with abundant hydrogen bonds as viscous self-healing polymer; Nano-SiO2 was hydrophobic modified by myristic acid (MA) as hydrophobic particles to construct rough surface structure. When the mass ratio of MA to SiO2 is 1∶1 and the modification time is 3 h, the superhydrophobic coating prepared has a contact angle of 152.61° and a sliding angle of 1.9°, which has excellent antifouling performance. The coating can be healed by simple heat treatment after being scratched by the blade, and has excellent self-healing performance. Compared with pure aluminum, the composite coating has better anti-corrosion performance and the corrosion inhibition efficiency can reach 87.53%. In addition, After 5 tape peel tests, linear wear tests with a wear length of 30 cm, ultrasonic shock tests of 50 min, 10 temperature differential cycles and 24 h ultraviolet irradiation, the contact angle remained above 150°, indicating that the coating has good mechanical stability and weather resistance. This study provides a new effective strategy for the preparation of self-healing superhydrophobic coatings, which is expected to be applied in the field of building antifouling.

     

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