纳米蛋黄核壳结构锂离子电池硅碳负极材料研究进展

Research progress of nano yolk-shell structured silicon/carbon anode materials for lithium-ion batteries

  • 摘要: 由于硅的大体积变化和电导率差等问题,这种容量高达4200 mA·h·g−1的负极材料难以实现商业化。蛋黄核壳结构的硅碳负极是目前锂离子电池硅碳负极材料研究的热点,该结构可以很好地缓解硅负极在充放电过程中因体积膨胀而引发的一系列问题,从而获得优越的储锂性能。本文对蛋黄核壳结构硅碳负极的碳源、结构类型和制备工艺等进行了分类和总结,并对一些重要的结构参数进行了阐述,展望了未来蛋黄核壳结构硅碳负极的发展方向。

     

    Abstract: Due to the large volume variation of silicon and the poor conductivity, it is difficult to commercialize this anode material with a capacity of up to 4200 mA·h·g−1. The silicon/carbon anode of the yolk-shell structure is currently a hot spot in the research of silicon/carbon anode materials for lithium-ion batteries, which can well alleviate a series of problems caused by volume expansion of silicon anode during the charging and discharging process, so as to obtain superior lithium storage performance. In this paper, the carbon source, structure type and preparation process of the silicon/carbon anode of the yolk-shell structure are classified and summarized, and some important structural parameters are elaborated, and the development direction of the silicon/carbon anode of the yolk-shell structure is prospected in the future.

     

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