CsPbBr3钙钛矿的光催化CO2还原研究进展

Research progress of photocatalytic CO2 reduction based on CsPbBr3 perovskite

  • 摘要: 探索绿色发展、解决能源危机已成为近年来商业发展的趋势。金属卤化物钙钛矿因其独特的光催化性能而备受关注。其中,CsPbBr3钙钛矿具有较高的光催化活性和优异的稳定性,在光催化CO2还原方面发展迅速。在能源发展趋势下,减少碳排放和催化还原CO2作为燃料是研究热点和主要途径。然而,纯CsPbBr3较差的CO2吸附还原能力、严重的电荷复合和较低的电荷效率严重阻碍了钙钛矿光催化的商业化。为了解决纯CsPbBr3材料光催化中的一系列问题,对CsPbBr3钙钛矿进行表面改性或构建多组分复合材料是目前最经济、最有前景的解决方案。本文讨论了CsPbBr3钙钛矿的光催化反应原理及所面临稳定性和还原能力的阻碍,对CsPbBr3钙钛矿及其复合物的光催化CO2还原研究进行了系统的回顾。最后对构建更加稳定、高效及可持续性的CO2还原光催化剂新的探索方向进行了展望。

     

    Abstract: Exploring green development and solving the energy crisis has become a trend of commercial development in recent years. Metal halide perovskites have attracted great attentions due to their unique photocatalytic properties. Among them, CsPbBr3 perovskite has high photocatalytic activity and excellent stability, and has developed rapidly in photocatalytic CO2 reduction. Under the trend of energy development, reducing carbon emissions and catalytic reduction of CO2 as fuels are research hotspots and main approaches. However, the poor CO2 adsorption capacity, severe charge recombination, and low charge efficiency of pure CsPbBr3 seriously hinder the commercialization of perovskite photocatalysis. In order to solve a series of problems in photocatalysis of pure CsPbBr3 materials, surface modification the of CsPbBr3 perovskite or construct on of multicomponent composites is currently the most economical and promising solution. In this review, we systematically review the latest research on photocatalytic CO2 reduction of CsPbBr3 perovskites and their composites, discuss the photocatalytic reaction mechanism of CsPbBr3 perovskites, and then propose obstacles to development. Finally, we expect this review to provide new exploration directions for building more stable, efficient and sustainable photocatalysts for CO2 emission reduction.

     

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