不同种类纤维增强复合材料湿热老化性能对比

Comparative study on the hygrothermal durability of different fiber reinforced composites

  • 摘要: 为研究碳纤维、玻璃纤维和植物纤维增强复合材料在湿热环境下的耐久性能差异,本文制备了纤维体积分数为60vol%的单向碳纤维/环氧树脂复合材料(Carbon fiber reinforced polymer,CFRP)、玻璃纤维/环氧树脂复合材料(Glass fiber reinforced polymer,GFRP)和亚麻纤维/环氧树脂复合材料(Flax fiber reinforced polymer,FFRP),在23℃、37.8℃和60℃下进行了吸水试验,并测试了三种复合材料在厚度方向的膨胀率、拉伸性能和层间剪切性能,同时利用时温等效原理对它们的长期吸水性能及力学性能进行了预测。结果表明,三种复合材料的吸水行为在老化前期均符合Fickian扩散定律,而后期有所偏离。从吸水性能来看,FFRP具有最高的扩散系数、饱和吸水率和膨胀率。从力学性能来看,CFRP的拉伸性能随老化时间的增加几乎不变,而层间剪切强度小幅下降,烘干后其拉伸性能及层间剪切性能与未老化时相同, CFRP在老化过程中未发生不可逆变化。GFRP老化后的拉伸强度和层间剪切强度下降幅度较大,而拉伸模量下降幅度较小,烘干后拉伸性能得到部分恢复,而层间剪切强度则基本未有任何恢复,GFRP在老化过程中发生了玻璃纤维水解及界面脱粘等不可逆变化。由于吸水后亚麻纤维的塑化,FFRP的拉伸强度略微提高,而拉伸模量和层间剪切强度则急剧下降后保持稳定,烘干后,其拉伸强度反而大幅下降,拉伸模量及层间剪切强度则大幅上升,这与水分的塑化作用、纤维及基体的膨胀和降解等变化有关。由三种复合材料的长期性能预测结果可知,CFRP的长期力学性能保持率较好,GFRP的长期力学性能保持率较差,FFRP在拉伸强度保持率方面具有优势,研究结果为湿热环境下工程结构的选材和设计提供了一定的理论依据。

     

    Abstract: Unidirectional carbon fiber reinforced epoxy resin composites (CFRP), glass fiber reinforced epoxy resin composites (GFRP) and flax fiber reinforced epoxy resin composites (FFRP) were manufactured with fiber volume fraction of 60vol% to compare the hygrothermal durability of composites. Water absorption tests were conducted at 23℃, 37.8℃ and 60℃. The swelling rate in the thickness direction, tensile properties and interlaminar shear properties were also monitored, and the time-temperature superposition principle was used to predict the water absorption and mechanical properties. The results show that the water absorption behaviors of three kinds of compo-sites conformed to Fickian's law in the early stage and gradually deviated in the later stage. In terms of water absorption performance, FFRP has the highest diffusion coefficient, saturation water absorption rate and swelling rate. In terms of mechanical properties, the tensile properties of CFRP are almost unchanged with the increase of aging time, while the interlaminar shear strength decreases slightly, and the tensile properties and interlaminar shear properties after drying are the same as those without aging, which indicate that no irreversible changes occurred in CFRP. The tensile strength and interlaminar shear strength of GFRP decrease a lot after aging, while the tensile modulus decrease less. The tensile properties are partially restored after drying, while the interlaminar shear strength is barely restored, which indicate that irreversible changes such as hydrolysis of glass fibers and interfacial debonding occurred during the aging process. Due to the plasticization of flax fibers after aging, the tensile strength of FFRP increase slightly while the tensile modulus and interlaminar shear strength decrease sharply and then remaine stable. After drying, the tensile strength decrease significantly, while the tensile modulus and interlaminar shear strength increase significantly, which are related to the changes of plasticization, expansion and degradation of fiber and matrix. From the long-term performance of the three kinds of composites, it can be seen that the long-term mechanical properties retention rates of CFRP are good, while that of GFRP are poor, and FFRP has an advantage in tensile strength retention rate. The results can provide a theoretical basis for the selection and design of engineering materials under hygrothermal environment.

     

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