助熔剂对可陶瓷化阻燃室温硫化硅橡胶泡沫性能的影响

Effect of flux agents on properties of ceramifiable flame retardant room temperature vulcanized silicone rubber foam

  • 摘要: 为提升室温硫化硅橡胶泡沫的阻燃性能和耐火性能,本文以不同熔点玻璃粉和硼酸锌为助熔剂,云母粉为耐火填料,制备可陶瓷化阻燃室温硫化硅橡胶泡沫,并研究了不同无机填料种类和配比对硅橡胶泡沫微观形貌、热稳定性、阻燃性能和燃烧行为的影响及不同温度烧蚀下硅橡胶泡沫的陶瓷化行为。结果表明,玻璃粉的引入影响了硅橡胶泡沫的发泡过程,形成了孔径较大的泡沫结构,不利于硅橡胶泡沫阻燃性能、热稳定性、火安全性的提升,但在烧蚀实验中,其能够显著降低硅橡胶泡沫的陶瓷化温度;硼酸锌的引入能够显著提升硅橡胶泡沫的阻燃性能、高温区热稳定性和火安全性,并且硼酸锌与云母粉展现出较好的协同阻燃作用,硅橡胶泡沫的极限氧指数(LOI)最高达到33.2%,并通过垂直燃烧FV-0级,N2气氛下热重分析测试中900℃时的残炭含量最高可达75.9%,硅橡胶泡沫的热释放和烟释放及烧蚀实验后的质量损失率均得到明显降低,同时,硼酸锌还有助于形成陶瓷状残炭。

     

    Abstract: In order to improve the flame retardancy and fire resistance of room temperature vulcanized (RTV) silicone rubber foam, glass powder and zinc borate as flux agent, and mica powder as refractory filler were used to prepare ceramifiable flame retardant RTV silicone rubber foam. The effects of different types and proportions of inorganic fillers on the micromorphology, thermal stability, flame retardancy and combustion behavior of the silicone rubber foam, as well as the ceramifiable behavior of the silicone rubber foam after ablation at different temperatures were studied. The results show that the introduction of glass powder affects the foaming process of the silicone rubber foam, forming a foam structure with large pore size, which is not conducive to the improvement of the flame retardancy, thermal stability and fire safety performances of the silicone rubber foam. But, glass power can remarkably decrease ceramization temperature of the silicone rubber foam. The introduction of zinc borate greatly improves the flame retardancy, thermal stability in high temperature zone and fire safety performances of the silicone rubber foam. Meanwhile, zinc borate and mica powder show good synergistic flame retardant effect. limiting oxygen index (LOI) value of the silicone rubber foam can reach to 33.2, and it can pass the vertical combustion FV-0 level. Carbon residue of the silicone rubber foam at 900℃ can reach up to 75.9% in thermogravimetric analysis in N2 atmosphere. The heat release, smoke release of the silicone rubber foam and the mass loss after the ablation experiment are significantly reduced. In addition, zinc borate also contributes to the formation of ceramic carbon residue.

     

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