石墨烯/碳纳米管共改性碳纤维复合材料的结构、力学、导电和雷击性能

Structure, mechanical property, electrical conductivity and lightning strike damage behavior of graphene/carbon nanotube co-modified CFRPs

  • 摘要: 发展结构-防雷击功能一体化复合材料是未来的发展方向之一。本文制备了一种石墨烯和碳纳米管共改性的复合材料并研究了其结构、力学性能、导电性能和雷击性能。结构研究表明导电纳米粒子主要分布于复合材料层间和邻近层间的层内区域,而内部分布较少。复合材料的0°弯曲强度和0°层间剪切强度分别为(1538±86) MPa和(107.0±1.0) MPa。制备了2 mm、3 mm、4 mm三种厚度的复合材料板,其面内电导率为100 S/cm左右,其厚度向电导率分别为0.128 S/cm、0.094 S/cm和0.088 S/cm。雷击试验表明,三种厚度试样的总损伤面积类似,深层损伤面积随厚度向电导率降低而减少,但损伤深度则随厚度向电导率降低而增加,损伤模式主要为树脂的烧蚀气化和纤维的断裂损伤,但没有明显的层间分层发生。2 mm厚雷击试样板损伤区域的最低弯曲强度达到了782 MPa,保持率为75%,弯曲模量保持率为59.2%。2 mm板和3 mm板雷击损伤中心150 mm×100 mm区域平均弯曲强度保持率分别达到了87.4%和87.2%,损伤深度分别只有约0.3 mm和0.4 mm。

     

    Abstract: Developing structural composites with integration of lightning strike resistance is one of the trend of developing new composites. In this paper, a composite co-modified with graphene and carbon nanotubes was prepared. Its microstructure, mechanical properties, electrical conductivity and lightning-strike properties were studied. Morphology study shows that the conductive fillers are mainly distributed in the interlayer and the adjacent intralaminar regions, while much less in the deep intralaminar regions. The composite has 0° flexural strength of (1538±86) MPa and 0° interlaminar shear strength of (107.0±1.0) MPa. Three laminates of 2 mm, 3 mm and 4 mm thickness were prepared for studying the electrical conductivity and lightning-strike properties. The in-plane conductivity of the composites is around 100 S/cm. The conductivity through thickness direction are 0.128 S/cm, 0.094 S/cm and 0.088 S/cm, respectively. The lightning-strike test shows that the total damage area of the three thickness samples is similar. The deep damage area decreases, while the damage depth increases with the decrease in conductivity through thickness direction. The damage mode is mainly the ablation damage of fiber and resin. No obvious delamination is found. The minimum flexural strength and the corresponding retention rates of the flexural strength and modulus of the damaged 2 mm thick laminate at the damage center are 782 MPa, 75% and 59.2%, respectively. The average flexural strength retention rates of the damage centers of the 2 mm and 3 mm thick laminates reached 87.4% and 87.2%, respectively. Their damage depths are only around 0.3 mm and 0.4 mm respectively.

     

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