MXene纤维的制备、性能及应用研究进展

Progress in preparation, properties and applications of MXene fiber

  • 摘要: 二维过渡金属碳/氮化物(MXenes)是一种新颖的二维纳米材料,具有优异的电学、力学性能及丰富的表面官能团,在功能材料领域受到了广泛关注,常被作为基元材料构筑宏观复合材料,其中MXene纤维有望成为继石墨烯纤维后另一种结构-功能一体化纤维材料,在多功能织物、传感、能源、电磁屏蔽等领域显示出巨大的应用前景。但目前MXene复合纤维的力学和电学性能与MXene纳米材料本征性能差距较大,主要原因是组装MXene纳米片过程中产生的褶皱、无序结构、界面作用力弱等问题,往往导致MXene纤维内部的孔隙、缺陷存在及纤维外形不规则等。针对MXene纤维研究过程中存在的问题及未来研究方向,本文做了详细综述,首先介绍MXene纤维的制备方法,然后详细阐述MXene复合纤维的力学和电学性能,并讨论提升其性能的策略。同时通过一些实例,综述了MXene复合纤维的应用。最后总结了MXene纤维存在的关键科学问题和挑战,并对MXene纤维的未来发展和前景进行了展望及对未来MXene纤维的研究和应用提供一些帮助。

     

    Abstract: 2D transition metal carbides and nitrides (MXenes) are a novel two-dimensional nanomaterial, which attracted extensive attention in the field of functional materials due to outstanding electrical, mechanical properties and abundant surface terminations. Therefore, it often has been used as building block for constructing macroscopic composites, such as MXene fibers, which are expected to be another structure-function integrated fiber after graphene fiber, and have widespread applications prospect in numerous fields, including smart textiles, sensing, energy, electromagnetic shielding, etc. However, the mechanical and electrical properties of MXene composite fibers are far lower than the intrinsic properties of MXene flakes. The main problems are that the existence of defects and voids in the MXene fiber caused by the wrinkling, disorder and weak interface interactions of MXene flakes during assembly, as well as the irregular shape of the fibers. In view of the existing problems as well as the future development direction, this review first introduces the fabrication approaches of MXene fiber. Then, we statement the mechanical and electrical properties of MXene composite fibers in detail, and discuss the strategies for improving the mechanical and electrical properties. Meanwhile, we outline the applications of MXene composite fibers by some instances. Finally, the existing scientific problems and challenges of MXene fiber are summarized, and the upcoming trends in MXene fiber are prospected, and some helpful viewpoint is provided for the research and application of MXene fiber in the future.

     

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