碳化物陶瓷颗粒对双相高熵合金基复合材料微观组织和力学性能的影响

Effect of carbide ceramic particles on the microstructure and mechanical properties of dual-phase high-entropy alloy matrix composites

  • 摘要: 高熵合金拓宽了复合材料中金属基体的选用范围。本文通过外加碳化物陶瓷颗粒,利用电弧熔炼技术制备Fe49.5Mn30Co10Cr10X0.5 (X=B4C、ZrC和TiC)等3种高熵合金复合材料,系统研究3种碳化物陶瓷颗粒对双相高熵合金基复合材料微观组织和力学性能的影响。研究结果表明:掺杂碳化物陶瓷颗粒均可细化高熵合金基体的晶粒尺寸,稳定fcc相,抑制hcp相形成,其中B4C陶瓷颗粒细化晶粒和稳定fcc相效果最显著。掺杂ZrC和B4C陶瓷颗粒样品,力学性能低于高熵合金基体样品,归因于ZrC和B4C陶瓷颗粒与基体之间的界面结合情况不佳,界面处出现孔洞性缺陷;而掺杂TiC陶瓷颗粒样品,其强韧化效果显著,归因于良好的界面结合、细晶强化、弥散强化及颗粒承载强化等。

     

    Abstract: The emergence of new high-entropy alloys has broadened the selection range of metal matrix compo-sites. In this study, carbide ceramic particles doped in Fe49.5Mn30Co10Cr10X0.5 (X=B4C, ZrC and TiC) high-entropy alloy composites are prepared by using arc melting technology, and the effects of three carbide ceramic particles on the microstructure and mechanical properties of composite materials were systematically studied. The results show that the doped carbide ceramic particles can refine the matrix grains, stabilize the fcc phase, and inhibit the formation of the hcp phase. Among them, B4C ceramic particles have the most significant effect on refining grains and stabilizing fcc phase. The mechanical properties of the samples doped with ZrC and B4C ceramic particles are lower than the matrix samples, which is attributed to the poor bonding between the ceramic particles and the matrix, and the appearing void defects at the interface. But TiC doped sample, the strengthening and toughening effect is significant, which is attributed to good interface bonding, fine grain strengthening, Orowan strengthening, and load bearing strengthening.

     

/

返回文章
返回