基于纤维素及其衍生物的凝胶材料设计

Design of gel materials with cellulose and its derivatives

  • 摘要: 凝胶(水凝胶与气凝胶)是一种具有多孔结构的三维材料,其在诸多领域具有广泛应用。纤维素的可降解性及生物相容性等特性使其在凝胶材料设计中备受关注,前景巨大。纤维素及其衍生物通常可通过溶解或在水溶液中均匀分散形成稳定的体系,再经适当交联制成水凝胶。纤维素气凝胶一般是由水凝胶经超临界干燥或冷冻干燥处理制得。系统总结了纤维素基水凝胶的制备方式及机制,分析了气凝胶不同的干燥制备方式对其形态结构的影响,并重点讨论了纤维素基凝胶材料在环境保护、生物医学、能源存储等领域的应用进展,最后指出了该领域研究存在的问题并进行了展望。

     

    Abstract: Gel (hydrogel and aerogel) is a three-dimensional material of porous structures, which has found various applications. Cellulose has been widely studied in designing gel materials since it is inherently biodegradable and biocompatible. Cellulose and its derivatives can usually form a stable system by dissolving or uniformly dispersing in aqueous solution, and then be made into hydrogels via the proper crosslinking. In addition, cellulosic hydrogels can be further transformed into aerogels with supercritical drying or freeze drying. This work herein provides a systematical review of gel materials designed with cellulose and its derivatives. Firstly, a thorough analysis is implemented on the technologies in cellulosic hydrogel preparation and the mechanisms therein. The influence of different drying methods of aerogel on its morphology and structure are discussed. Furthermore, the applications of cellulosic gel in environmental protection, biomedicine, energy storage and other fields are summarized. Finally, the existing issues in this area are pointed out and prospected.

     

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