干法缠绕用预浸纱制备工艺优化及其性能

Preparation process optimization and performance of pre-impregnated yarn for dry winding

  • 摘要: 干法缠绕是缠绕成型工艺的重要分支,其缠绕过程含胶量均匀、缠绕效率高、环境污染小,更容易实现工业自动化生产。开发具有良好加工性能的预浸纱,对干法缠绕的推广应用具有重要意义。通过动态DSC和恒温DSC,结合流变测试,研究了所用环氧树脂体系固化特性,基于自催化模型建立树脂固化反应动力学方程,并与实测固化度对比验证。搭建预浸纱制备平台,采用改进热熔法制备干法缠绕用预浸纱,分析制备过程中不同固化度对预浸纱表面质量的影响。在此基础上通过响应面法分析不同工艺参数(纱架张力、收卷速率、烘道温度)对预浸纱含胶量的影响。结果表明:自催化模型与实验结果基本吻合,适用于干法缠绕预浸纱最佳固化度范围为5%~10%,对含胶量影响最大的因子是收卷速率,其次是放纱张力,烘道温度影响最小。综合考虑各工艺参数影响规律,获得优化的制备工艺参数:烘道温度为180℃,收卷速率为8 m/min,放纱张力为6 N,此时树脂含胶量为30.1wt%。NOL环拉伸强度可达2536.1 MPa,拉伸模量为162.3 GPa,层间剪切强度为57.3 MPa。

     

    Abstract: Dry winding is an important branch of the winding forming process. The winding process has uniform glue content, high winding efficiency, low environmental pollution and easier industrial automation production. The development of prepreg yarn with good processing properties is of great significance to the promotion and application of dry winding. Through dynamic DSC and constant temperature DSC, combined with the viscosity test, the curing characteristics of the epoxy resin system used were studied. Based on the autocatalytic model, the resin curing reaction kinetic equation was established and verified by comparison with the measured curing degree. A prepreg yarn preparation platform was set up, an improved hot-melt method to prepare dry winding prepreg yarn was adopted, and the influence of different curing degrees on the surface quality of prepreg yarn during the preparation process was analyzed. On this basis, the response surface method was used to analyze the influence of different process parameters (creel tension, winding speed, drying tunnel temperature) on the glue content of the prepreg yarn. The results show that the autocatalytic model is basically consistent with the experimental results, and the best curing range for dry winding prepreg yarn is 5%-10%. The factor that has the greatest influence on the glue content is the winding rate, followed by the unwinding tension. The temperature of the drying tunnel has the least influence. Considering the influence law of various process parameters, the optimized preparation process parameters are obtained: The temperature of the drying tunnel is 180℃, the winding speed is 8 m/min, the yarn unwinding tension is 6 N, and the resin mass fraction is 30.1wt% at this time. The tensile strength of the NOL ring can reach 2536.1 MPa, the tensile modulus is 162.3 GPa, and the interlaminar shear strength is 57.3 MPa.

     

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