纸浆纤维/聚乳酸复合材料的力学和热学性能

Mechanical and thermal properties of pulp fiber/polylactic acid composite

  • 摘要: 生物质衍生填料增强的生物复合材料一直被认为是极具潜力的石油基产品的替代品。引入高含量漂白纸浆纤维(10wt%~50wt%),使用辊磨挤出法和密炼法两种预混工艺,采用马来酸酐接枝聚丙烯(MA-g-PP)为相容剂,制备了纸浆纤维/聚乳酸(PLA)复合材料。采用拉伸测试、SEM、FTIR、DMA和TGA表征,综合考察了制备工艺和纤维含量对复合材料的力学性能、热学性能和微观结构的影响。结果表明:密炼法比辊磨挤出法更有效地实现了纤维在基体中的良好分散(几乎定向排列)。50wt%纤维含量的密炼加工复合材料实现了最大的拉伸强度(50.49 MPa,略高于PLA)和最高的弹性模量值(2.56 GPa,比PLA高45.8%)。刚性填充的纸浆纤维降低了复合材料的阻尼性能,损耗因子tanδ峰值温度发生正迁移。纸浆纤维不会对热稳定性产生不利影响,复合材料的残留物含量提高。研究表明,漂白纸浆纤维增强改性PLA制造可生物降解的复合材料是可行的。

     

    Abstract: Biomass-derived fillers reinforced composites have always been considered as potential substitutes for petroleum-based products. In this work, high content of bleached pulp fibers (10wt% to 50wt%) were adopted to modify polylactic acid (PLA) with maleic anhydride grafted polypropylene (MA-g-PP) as the compatibilizer. Two pre-melting processes of fiber/PLA composites were tried, i.e., roll-grinding plus extruding as well as internal mixing process. Tensile test, SEM, FTIR、DMA and TGA were employed to comprehensively investigate the effects of processing methods and fiber content on the mechanical and thermal properties, and microstructure of fiber/PLA composites. The results showed that, internal mixing process (IM process) is more effective than grinding and extruding process (GE process) to achieve good dispersion and almost oriented-arrangement of the fibers in the matrix. IM-processed composites with fiber content up to 50wt% acquired the maximum tensile strength (50.49 MPa, slightly higher than PLA) and Young's modulus (2.56 GPa, 45.8% higher than PLA). Damping capacity and loss factor of composites are reduced by the rigid filled pulp fibers, while the peak temperature is positively migrated. Pulp fibers added have no adversely effect on thermal stability and improve the residues content of PLA composites. It can be concluded that bleached pulp fiber is an effective filler for PLA-based composites.

     

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