回收碳纤维混凝土导电性

Conductivity of recycling carbon fiber concrete

  • 摘要: 碳纤维增强树脂复合材料从生产、服役到退役的整个生命周期都会产生巨量废弃物,带来了严重的环境污染与资源浪费问题。本文将生产过程中产生的废弃碳纤维掺加到混凝土中,研究其对混凝土强度及导电性的影响规律与机制。结果表明,回收碳纤维对混凝土强度改善效果不明显,这是由于工业碳纤维表面的涂层使其在混凝土拌合过程中更易聚集成束,不易分散。回收碳纤维的掺入可明显提升混凝土导电性,掺量为0wt%~0.3wt%时,干燥/吸水过程改变混凝土孔结构且C—S—H凝胶重新排列、局部收缩与部分不可逆特性使混凝土产生新的导电路径,电阻率随含水率降低呈现先升后降的趋势;掺量为0.4wt%~1.5wt%时,混凝土内部形成了稳定的物理接触导电网络,龄期及含水率对导电率无明显影响。

     

    Abstract: The whole life cycle of carbon fiber reinforced polymer composite from production, service to retirement will produce huge amount of waste, bringing serious environmental pollution and resource waste. In this paper, the waste carbon fiber produced in the production process was added to the concrete to study its influence law and mechanism on the strength and conductivity of concrete. The results show that the recovery effect of carbon fiber on the strength of concrete is not obvious, because the coating on the surface of industrial carbon fiber makes it easier to gather into bundles and not easy to disperse in the process of concrete mixing. The incorporation of recycling carbon fiber can significantly improve the conductivity of concrete. When the content of recycling carbon fiber is 0wt%-0.3wt%, the drying/water absorption process changes the pore structure of concrete. And the C—S—H gel rearrangement, local shrinkage and partial irreversible characteristics make concrete produce a new conductive path. The resistivity increases first and then decreases with the decrease of water content. When the content is 0.4wt%-1.5wt%, a stable physical contact conductive network is formed in the concrete, and the age and moisture content have no obvious effect on the conductivity.

     

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