石墨含量对铜-石墨-乳化沥青复合材料组织和性能的影响

Effects of graphite content on microstructure and properties of Cu-graphite-emulsified asphalt composites

  • 摘要: 以电解铜粉与石墨粉为原料,阴离子乳化沥青为粘结剂,采用粉末冶金技术制备了铜-石墨-乳化沥青复合材料,并通过XRD、EDS和SEM对石墨含量为2wt%~8wt%的铜-石墨-乳化沥青复合材料微观组织进行表征,研究了铜-石墨-乳化沥青复合材料的摩擦磨损性能、力学和电学性能,并与不含乳化沥青的铜-石墨复合材料进行比较。结果表明,乳化沥青可以有效防止石墨颗粒的聚集,对石墨和铜基体起粘结作用;在两相界面处几乎没有间隙,并且产生了层片状石墨;石墨含量为4wt%的试样磨损量最小,仅为0.0049 g,摩擦系数约为0.025;增加载荷和石墨含量会增大磨损量,但会降低摩擦系数;在滑动摩擦期间,磨损表面会出现裂纹、犁沟、凹陷、小颗粒和层片状结构,但其程度要比不含乳化沥青的复合材料低。

     

    Abstract: Using electrolytic copper powder and graphite powder as raw materials, anionic emulsified asphalt as binder, the Cu-graphite-emulsified asphalt composites were prepared by powder metallurgy technology, and XRD, EDS and SEM were used to characterize the microstructure of Cu-graphite-emulsified asphalt composites with graphite content of 2wt%-8wt%. The friction and wear properties, mechanical and electrical properties of Cu-graphite-emulsified asphalt composites were studied, and compared with those of Cu-graphite composites without emulsified asphalt. The results show that emulsified asphalt can effectively prevent the aggregation of graphite particles and has a bonding effect on the graphite and Cu matrix; At the interface of the two phases, there is almost no gap and layered graphite being produced; The sample with 4wt% graphite has minimum wear loss of only 0.0049 g, and the friction coefficient is about 0.025; Increasing the load and graphite content will increase the wear loss, but it can reduce the friction coefficients; During sliding friction, cracks, chutes, depressions, small particles and lamellar structures will appear on the worn surface, but the extent is lower than that of composites without emulsified asphalt.

     

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