量子点/TiO2复合光催化材料的研究进展

Research advances on quantum dots/TiO2 composite photocatalytic materials

  • 摘要: 近年,光催化技术已被广泛应用于污水处理、CO2还原、制氢等多个领域。在光催化材料中,TiO2由于具有化学稳定性高、来源广泛、价格低廉等优点,应用最广泛。但较宽的带隙及较高的电子及空穴复合效率使TiO2的光催化性能受到极大限制。量子点(QDs)作为一种受量子约束效应影响的纳米尺度粒子,具有载流子易调控和表面位点丰富等优势。因此,研究人员采用不同方法将TiO2与QDs复合,以增强TiO2的光催化性能,获得了系列具有优异光催化性能的QDs/TiO2复合光催化材料。本文主要综述了QDs/TiO2复合光催化材料的研究进展。首先,阐述了QDs/TiO2复合光催化材料的制备方法,并就QDs对TiO2光催化性能的增强机制进行了剖析;然后,总结了QDs/TiO2复合光催化材料在有机污染物降解、制氢及CO2还原方面的应用研究进展;最后,围绕QDs/TiO2复合光催化材料现阶段研究中的关键问题及未来的研究前景进行了展望。

     

    Abstract: In recent years, photocatalytic technology has been widely used in sewage treatment, CO2 reduction, hydrogen production and other fields. Among photocatalytic materials, TiO2 is widely used due to its advantages of high chemical stability, wide sources and low price. However, wide band gap and high electron and hole compound efficiency greatly limit the photocatalytic performance of TiO2. Quantum dots (QDs), a kind of nano-scale particles affected by quantum constraint effect, show the advantages of easy carrier regulation and abundant surface sites. Therefore, different methods have been used by researchers to compound TiO2 with QDs for the enhancement of photocatalytic performance of TiO2, and then a series of QDs/TiO2 composite photocatalytic materials with excellent photocatalytic performance are obtained. This review mainly introduces the research progress of QDs/TiO2 composite photocatalytic materials. Firstly, the preparation methods of QDs/TiO2 composite photocatalytic materials were described, and the enhancement mechanism of TiO2 photocatalytic performance by QDs was analyzed. Then, The application of QDs/TiO2 composite photocatalytic materials in the degradation of organic pollutants, hydrogen production and CO2 reduction were summarized. Finally, the major issues in the current research of QDs/TiO2 composite photocatalytic materials and the future research prospects were discussed.

     

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