微胶囊化膨胀型阻燃剂与有机蒙脱土协效阻燃乙烯-醋酸乙烯共聚物性能

Synergistic properties of microencapsulated intumescent flame retardant-organically modified montmorillonite/ethylene-vinyl acetate copolymer composites

  • 摘要: 通过纳米复合的方式,将微胶囊化的膨胀型阻燃体系—聚磷酸铵(APP)-季戊四醇(PER)与有机改性的片层蒙脱土(OMMT)用于协效阻燃乙烯-醋酸乙烯共聚物(EVA)。采用XRD、TEM、TGA、极限氧指数(LOI)、垂直燃烧(UL-94)、锥形量热仪、烟密度和动态机械热分析对微胶囊化APP(MCAPP)-微胶囊化PER(MCPER)-OMMT/EVA复合材料的结构与性能进行研究。研究结果表明,OMMT被完全剥离开,并以层离或插层的状态分散在EVA中;MCAPP-MCPER与OMMT之间存在明显的协效阻燃作用,用3wt%OMMT代替MCAPP-MCPER后,MCAPP-MCPER-OMMT/EVA复合材料的LOI值从25.5vol%提高到29.5vol%,垂直燃烧结果由V-2上升到V-0级别,残炭量也由14.5wt%增大到15.9wt%,烟密度由154.7 g/s降低到97.5 g/s,材料的阻燃性能得到有效提高。此外,万能拉伸测试及动态机械热分析测试表明,通过纳米复合制备的阻燃MCAPP-MCPER-OMMT/EVA复合材料具有更好的力学和动态热机械性能。

     

    Abstract: Flame retardant ethylene-vinyl acetate (EVA) composites were prepared by combination of microencapsulated intumescent flame retardants-ammonium polyphosphate (APP)-pentaerythritol (PER) and organically modified montmorillonite (OMMT). The microencapsulated APP (MCAPP)-microencapsulated PER (MCPER)-OMMT/EVA composites were further characterized through XRD and TEM, confirming OMMT sheets are well dispersed in the matrix as exfoliated or intercalated nanocomposite state. Limiting oxygen index (LOI), TGA, underwriters laboratories 94 vertical burning (UL-94), cone and smoke density test results indicate the synergistic flame retardancy effect between MCAPP-MCPER and OMMT in MCAPP-MCPER-OMMT/EVA composites. Replacing the same amount of MCAPP-MCPER with 3wt% OMMT could improve the LOI value of the MCAPP-MCPER-OMMT/EVA composites from 25.5vol% to 29.5vol%. The UL-94 rating increases from V-2 to V-0. The char residue of MCAPP-MCPER-OMMT/EVA composites is improved from 14.5wt% to 15.9wt% and the smoke density significantly decreases from 154.7 g/s to 97.5 g/s. Besides, the mechanical property of MCAPP-MCPER-OMMT/EVA composites was tested by universal testing machine and dynamic thermomechanical analysis (DMA), the result shows that the flame-retardant MCAPP-MCPER-OMMT/EVA composites has better mechanical properties.

     

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