空心玻璃微珠/全芳香族共聚酯复合泡沫的构筑及其热学性能

Construction and enhanced thermal properties of hollow glass beads/ aromatic thermosetting polyester composite foam

  • 摘要: 本研究将空心玻璃微珠(HGB)引入到全芳香族热固性共聚酯(ATPE)发泡体系中制备了HGB/ATPE复合泡沫,并研究了HGB的含量和泡沫性能对于复合泡沫体系的影响。当玻璃微珠改性后,HGB/ATPE复合泡沫的比强度为26.2 MPa/(g·cm−3);HGB的加入也使复合体系热性能和阻燃性能有较大提高,HGB/ATPE复合泡沫的热分解温度、玻璃化转变温度及热变形温度分别为494.18℃、230.47℃和191.00℃,极限氧指数可达到35%~37%。

     

    Abstract: In this study, hollow glass beads (HGB) were introduced into an aromatic thermosetting polyester (ATPE) based foam to prepare HGB/ATPE composite foam, and effect of content of HGB and foaming conditions on the properties of HGB/ATPE composite foam were investigated. After modification, the specific strength of the HGB/ATPE composite foam can reach 26.2 MPa/(g·cm−3), respectively. Moreover, the addition of HGB also greatly improves thermal properties and flame resistance performance of the HGB/ATPE composite foam. The thermal decomposition temperature, glass transition temperature and heat distortion temperature of the HGB/ATPE composite foam are 494.18℃, 230.47℃ and 191.00℃, respectively, and the limiting oxygen index can reach 35%–37%.

     

/

返回文章
返回