活性炭/高密度聚乙烯复合材料的力学性能

Mechanical properties of activated carbon/high density polyethylene composites

  • 摘要: 以稻壳为原料,以H3PO4、KOH、ZnCl2为活化剂在600℃条件下制备三种活性炭,以生物炭、三种活性炭为填料填充高密度聚乙烯(HDPE)制备生物炭/HDPE复合材料和活性炭/HDPE复合材料,并对其力学性能进行测试和分析。结果表明,活性炭比生物炭具有更高的比表面积和发达的孔隙结构,其中经H3PO4活化制备的活性炭比表面积最高,为714.27 m2/g;活性炭/HDPE复合材料比生物炭/HDPE复合材料具有更佳的力学性能,相对于其他材料而言,经H3PO4活化制备的活性炭/HDPE复合材料具有较佳的弯曲性能、拉伸性能、刚性、弹性、抗蠕变性能及抗应力松弛能力,其弯曲强度、弯曲模量、拉伸强度、拉伸模量分别为38.66 MPa、2.46 GPa、32.17 MPa、1.95 GPa。本研究可为活性炭的材料化利用提供有益的借鉴经验。

     

    Abstract: Three kinds of activated carbon were prepared from rice husk with H3PO4, KOH, ZnCl2 as activating agents at 600℃. The biochar and three kinds of activated carbon were used to reinforce high density polyethylene (HDPE) to prepare biochar/HDPE composites and activated carbon/HDPE composites. The mechanical properties of the composites were tested and analyzed. The results show that higher specific surface area and more developed pore structure are obtained in activated carbon than in biochar, and better mechanical properties are obtained in activated carbon/HDPE composites than biochar/HDPE composites. Besides, the highest specific surface area of 714.27m2/g is obtained in activated carbon which is activated by H3PO4 (activated carbon(H3PO4)), and better comprehensive mechanical properties are obtained for activated carbon(H3PO4)/HDPE composite due to its excellent flexural properties, tensile properties, rigidity, elasticity, creep resistance and anti-stress relaxation ability. The flexural strength, flexural modulus, tensile strength and tensile modulus of the activated carbon(H3PO4)/HDPE composite are 38.66 MPa, 2.46 GPa, 32.17 MPa and 1.95 GPa, respectively. This study can provide useful experience for utilization of activated carbon in composites.

     

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